Lectures in Paleomagnetism, 2005
by Lisa Tauxe


Citation and Home Page:
http://earthref.org/MAGIC/books/Tauxe/2005/

June 13, 2005

Chapter 15
The GPTS and magnetostratigraphy

Suggested Reading
For background:
Chapter 9: Butler (1992)
Chapters 4 & 5: McElhinny and McFadden (2000)
To learn more:
Opdyke and Channell (1996)
Oreskes (2001)
Glen (1982)
www.stratigraphy.org
Gradstein et al., 2004

15.1 Introduction

The geological time scale is a list of ordered events placed in a temporal/spatial context. Time (see Figure 15.1) is broken into Eons (e.g., Phanerozoic, Proterozoic), Eras (e.g., Mesozoic, Cenozoic), Periods (e.g., Cretaceus, Paleogene), Series (e.g, Oligocene, Miocene) and Stages (e.g, Messinian, Zanclean). The fundamental unit, the stage is ideally defined by its base at a particular place and many such “Global Standard Section and Points”, or GSSPs have been identified. Numerical ages are attached to these stage boundaries by a variety of methods. Some methods have explicit numerical age control (e.g., from the predictable decay of radioactive isotopes or variations in climate caused by the relationship of the Earth and the sun), while others have only relative age information (e.g., the progressive change of fossil assemblages, or the identification of contemporaneous events in the geological record). Almost always numerical ages are estimated by correlation, interpolation, and/or extrapolation. As such, the geological time scale is a work in constant revision. The most recent is that of Gradstein et al. (2004), which will probably be the standard for about a decade.

One of the important tools in assembling the geological time scale is the geomagnetic polarity time scale (GPTS). Identification of a particular polarity reversal allows direct correlation of isochronous events between continental and marine sequences, between northern and southern hemispheres and between the Pacific and Atlantic realms. Apart from the identification of unique ash layers or the very rare geochemical tracers like an iridium spike, there is no better way to tie together the stratigraphic record. In this lecture we will review how the modern GPTS was constructed and will briefly consider some applications of the GPTS to geological problems.



Figure 15.1: The International Stratigraphic Chart. (See interactive version at: http://www.stratigraphy.org/.)


15.2 Early efforts in defining the GPTS

We learned in Lecture 14that early workers discovered reversely magnetized rocks in the early 20th century, and some suspected that there was a globally synchronous pattern of polarity reversals (e.g., Matuyama, 1929). However, it was not until combined studies of both age (using the newly developed age dating technique using the decay of radioactive potassium to argon) and polarity (from globally distributed lava flows) that the first Geomagnetic Polarity Time Scales (GPTS) began to take shape (Figure 15.2; see e.g., Cox et al., 1963, 1964).



Figure 15.2: Magnetic polarities from volcanic units plotted against age as determined by the potassium-argon method. The first three long intervals were named after famous geomagnetists. [Figure from rom Cox et al., 1964].


Cox et al. (1964) broke the polarity sequence into times of dominantly normal polarity (i.e., the field vector more or less parallel to today’s field) and times of dominantly reverse polarity (i.e., the field vector more or less antipodal to today’s field). They called these time units “Epochs” (note that they are now known as Chrons). The first three were named after some major players in geomagnetism: B. Brunhes (who first discovered reversely magnetized rocks), M. Matuyama (who first saw that the reversely magnetized rocks were older than the normal ones), and F. Gauss (who worked out the first geomagnetic field model). A fourth was later named after W. Gilbert (who first realized that the Earth itself was a magnet). Cox et al. (1964) also recognized the existence of shorter intervals which they called “Events” (e.g., the Olduvai and Mammoth events in Figure 15.2; note that events are now known as sub-chrons). These shorter intervals are traditionally named after the place where they were first documented.

Time scales constructed in the manner of Cox and colleagues based on discrete polarity, date pairs are necessarily limited by the uncertainty in the dating of young basalts. In the early 60’s this uncertainty exceeded the average duration of polarity intervals for times prior to about five million years (except for the very long intervals of a single polarity like the Permian “Kiaman” interval which lasted over 50 million years).



Figure 15.3: Map of the pattern of magnetic anomalies off northwestern North America. [Modified from Mason and Raff, 1961.]


Shortly after the publication of Cox et al. (1963) and McDougall and Tarling (1963), which essentially laid to rest doubts about the validity of geomagnetic reversals and sketched the rudiments of the first GPTS, Vine and Matthews (1963) put ideas about polarity reversals and the bizarre “magnetic stripes” in marine magnetic anomaly data (Figure 15.3; e.g., Mason and Raff, 1961) together as strong proof of sea floor spreading. The realization that the marine magnetic anomalies were a record of polarity history meant that the template for the pattern of reversals could be extended far beyond the resolution of the K-Ar method (see Figure 15.4, e.g., Pitman and Heirtzler 1966). It was not long before such a template for paleomagnetic reversals based on magnetic anomalies (numbering 1 to 31) was proposed. By assigning an age of 0 Ma to the ridge crest, an age of 3.35 Ma to the of the Gauss/Gilbert boundary (stars in Figure 15.4) and assuming constant spreading for the South Atlantic anomaly sequence, Heirtzler et al. (1968) produced a GPTS that extended to about 80 Ma. The age of anomaly 31 was estimated to be about 71.5 Ma. The truly astounding thing is that the currently accepted age for anomaly 31 is about 68 Ma (e.g., Cande and Kent, 1995) a difference of only a few percent!



Figure 15.4: A profile of bathymetry (bottom panel) and magnetic anomalies (labelled “profile”) obtained from the East Pacific Rise (Eltanin 19 profile, also known as “the magic profile”.) The magnetic anomaly profile, flipped east-to-west is replotted above (labelled “profile backwards”). Assuming a magnetization of a 500 m thick section of oceanic crust (black and white pattern above), a model for the predicted anomalies could be generated (labelled “model”). Above is the inferred time scale. The position of the Gauss/Gilbert boundary is marked by stars. [Adapted from Pitman and Heirtzler, 1966.]


In a parallel effort to the marine magnetic anomaly work, several groups were investigating the magnetic stratigraphy of deep sea sediment cores (e.g., Harrison, 1966 and Opdyke et al. 1966). In Figure 15.5 we show the record of inclination versus depth of Opdyke et al., (1966) obtained from a core taken off the coast of Antarctica. Upwardly pointing (negative) inclinations are normal and positive inclinations are reversely magnetized. This polarity pattern was correlated to the currently available time scale which included the new “event” known as the Jaramillo (Doell and Dalrymple, 1966) and revised age estimates for the “epoch” boundaries.



Figure 15.5: left: Inclinations from core V16-134 plotted against depth. middle: The GPTS as it was known in 1966. Faunal zones of the southern ocean identified within the core. [Adapted from Opdyke et al., 1966.]


The polarity sequence from magnetostratigraphic records was extended back into the Miocene by Opdyke et al. (1974, see Figure 15.6). The epochs, defined by the magnetostratigraphy could not easily be correlated to the anomaly data shown in Figure 15.4 and the two numbering schemes (anomaly numbers and epoch numbers) remained separate until the correlation between the two was deemed sufficiently robust.

15.2.1 A note about terminology

The Epoch/Event terminology was changed to Chron/sub-chron in 1979 by international agreement (Anonymous, 1979). Along with chrons and sub-chrons, the international subcommission defined “superchrons”. Cande and Kent (1992) later defined “cryptochrons”. Superchrons are extremely long polarity intervals, such as the Kiaman (also known as the Permo-Carbaniferous Reverse Superchron or PCRS) which lasted from 298 to 265 Ma (Gradstein et al., 2004) and the Cretaceous Normal Superchron (CNS: 84-125 Ma in Gradstein et al., 2004) Cryptochrons are “tiny wiggles” in the marine magnetic anomaly record that are too short to be unequivocally interpreted as full reversals (i.e., shorter than about 30 kyr). Some of these may be related to geomagnetic “excursions” (see Lecture 14.)

In an attempt to rationalize the Neogene chron (event) terminology (which numbered chrons from 5-22) and the anomaly terminology (running from 1 to about 6C), Cande and Kent (1992) broke the time scale into chrons and sub-chrons based on the anomaly numbering scheme distinguishing chrons from anomalies with the letter “C”. Because the anomaly numbering system only had 34 anomalies from the end of the CNS to the present, many more subdivisions were required, particularly in the very “busy” interval between Anomalies 5 and 6. These anomalies are denoted 5’ 5A, 5AA, 5AB and the like, so the present Neogene GPTS is a nightmare of chron and sub-chron names like C4n.1r or C5ADr where the “n”s and “r”s refer to polarity and the .1s refer to sub-chrons within chrons (e.g, C4n). For a complete listing of the GPTS since the CNS, please refer to the Appendix.

15.2.2 The addition of biostratigraphy

An interesting aspect to the magnetostratigraphic work typified by Opdyke et al. (1966) was the identification of biostratigraphic zones (_O_ to f in Figure 15.5) based on faunal assemblages in the core. These zones are therefore tied directly to the magnetostratigraphic record. The addition of biostratigraphy to the GPTS problem brought new possibilities for the calibration of the time scale in that certain boundaries could be dated by radioisotopic means using datable layers (e.g., ash beds) within stratigraphic sections. If a particular well dated biostratigraphic horizon could be tied to the magnetostratigraphic record, then the associated numerical ages could be attached to the GPTS. Exploiting this possibility, LaBrecque et al. (1977) used the magnetostratigraphic record in Italian carbonates (e.g., Alvarez et al., 1977) which tied the Cretaceous/Tertiary (K/T) boundary to a reverse polarity zone between two normal polarity intervals correlated with marine magnetic anomalies 29 and 30. The accepted age for the K/T boundary at the time was 65 Ma (van Hinte, 1976) which is virtually identical to the currently accepted age of 65.5± 0.3 Ma (Gradstein et al., 2004), so ages for the anomalies numbered 1-34 could be estimated by interpolation and extrapolation. Note that anomaly 14 is now thought to be a cryptochron (S. Cande, pers. comm.) and has not been included as a numbered anomlay in timescales since LaBrecque et al., 1977.)



Figure 15.6: Declinations from deep-sea piston core RC12-65 from the equatorial Pacific Ocean (using an arbitrary zero line because the cores were not oriented). The epoch system of magnetostratigrahic nomenclature was extended back to Epoch 11 in this core and to Epoch 19 in companion cores. [Figure from Opdyke et al., 1974].


15.2.3 Astrochronology

Until 1990, the GPTS was dated using numerical ages based on the decay of radioactive elements (largely the K/Ar method). An alternative approach to dating of stratigraphic sequences long in use is based on the climatically induced changes in lithology or stable isotopic records in sediments that are caused by variations in the Earth’s orbit around the sun. The relationship of the Earth’s orbit to the sun results in changes in the amount and latitudinal distribution of solar radiation (so-called “insolation”) reaching the Earth as a function of time. According to the Milankovitch hypothesis (e.g., Hays et al. 1976), changes in insolation at high northern latitudes vary with periodicities reflecting precession (with a beat of around 21 kyr), obliquity (~ 40 kyr) and eccentricity (~ 100 kyr). These cahnges in insolation resulted in measurable changes in the chemistry of the oceans and atmospheres and left an indelible mark on the lithostratigraphy (e.g., variations in carbonate) and the isotopic ratios of oxygen (the light isotope 16O gets preferentially incorporated into glacial ice at high latitudes, leaving the oceans richer in 18O.) Because the precession, obliquity and eccentricity of Earth’s orbit can be robustly predicted as a function of age at least for several million years (and perhaps even 10s of millions of years), identification of these patterns in the stratigraphic record allow numerical ages to be attached to the sedimentary sequence. This is a method known as “astrochronology”. Starting with Shackleton (1990) and Hilgen et al. (1991), astrochronology has been applied to the GPTS (see e.g., Figure 15.7).



Figure 15.7: Illustration of the “astrochronology” dating method. The sequence of polarity intervals and climatically induced sapropel layers is correlated to the GPTS (left) and the orbital cycles (right). The numerical ages from the orbital cycles can then be tranferred to the GPTS. [Adapted from Hilgen et al., 1991.]




Figure 15.8: Left: Lithostratigraphic and magnetostratigraphic pattern derived from overlapping drill cores into the Newark Basin. Right: Interpretation for the GPTS based on astrochronology and correlation to the Geological Time Scale. [Adapted from Kent et al., 1995 and Kent and Olson, 1999.]




Figure 15.9: The Neogene of the Geological Time Scale. [Figure from Gradstein et al., 2004.]


15.2.4 The Mesozoic and beyond

By the early 70s the large scale structure of the marine magnetic anomalies had been sketched out. There was a young set numbered 1-34 which terminated in a vast expanse of oceanic crust with no correlatable anomalies known as the “Cretaceous Quiet Zone” or CQZ. The Cretaceous Quiet Zone is well established as being a period of time with very few (or no!) reversals. The CQZ is synonymous with the Cretaceous Normal Superchron, or CNS and extends from the middle of the middle of the Santonian (~ 84 Ma) to the middle of the Aptian stage (~ 125 Ma). On the old end of the CQZ was another set of anomalies, known as the “M-sequence” (e.g., Larson and Heirtzler, 1972). These extend from M0 (which bounds the old end of the CQZ) to M25 based on marine magnetic anomalies.

Because the oldest sea floor is about 180 Ma and the oldest marine magnetic anomaly sequence is very poorly expressed (it is known as the “Jurassic Quiet Zone”), polarity intervals older than about M25 are defined using various magnetostratigraphic sections obtained from land exposures. The M-squence of polarity intervals was extended to about M39 using sections from Spain and Poland. The M-sequence has now been fairly firmly tied to geological stages and thereby calibrated in terms of numerical ages (see e.g., Gradstein et al., 2004).

As we go back farther in time, the GPTS necessarily becomes more sketchy. What is required is long sequences of stratigraphic sections with few gaps and reasonably constant sediment accumulation rates. Such sequences are difficult to identify and piece together so the GPTS will only slowly be completed.

One very long part of the GPTS in the middle to late Triassic is, however, quite well known. Using a series of drill cores with overlapping sections, Kent et al. (1995) defined a set of polarity intervals labelled E1 to E23 (see Figure 15.8). Kent and Olson (1999) interpreted lithologic cycles within sections as 400 kyr climatic cycles and calibrated their composite depth scale to time. Their resulting time scale is shown to the right in Figure 15.8.

Painstakingly acquired overlapping stratigraphic sections will be the basis for future extensions of the GPTS. Stay tuned - this is very much a work in progress and is advancing rapidly.

15.3 Current Status of the Geological Time Scale.

For reference, we include the dates of the most recent GPTS in the Appendix. As an example of the detailed correlations between the polarity time scale and various biological time scales, we show the Neogene portion from Gradstein et al. (2004) in Figure 15.9. For details, the reader is referred to the original reference. Please note that the time scale is a consensus document that balances a tremendous amount of information from a variety of sources. As such, it is subject to change, although not change should not be frequent or drastic.



Figure 15.10: Plot of distance from the ridge crest in the South Atlantic versus age using the GPTS of Gradstein et al., (2004). The differential of this curve gives instantaneous spreading rate.


15.4 Applications

15.4.1 Dating geological sequences

An important application of the fact that the geomagnetic field undergoes frequent reversals, whose ages are fairly well known, at least for the last hundred million years or so, is to use the GPTS as a dating tool for stratigraphic sequences. The pattern of polarity zones is determined by measuring the magnetization of samples taken from the stratigraphic section. If the polarity zones in the so-called magnetostratigraphy can be unambiguously correlated to the GPTS, they constitute a precise temporal framework for sedimentary or volcanic sequences. Such records have proved invaluable for correlating stratigraphic information on a global basis and are the primary means for calibrating the Cenozoic fossil record with respect to time. Furthermore, knowing the ages of polarity reversals allows the calculation of rates of processes such as sea-floor spreading, sediment accumulation, extinctions and speciation and provide independent verification of orbital calculations.

Sedimentation is not always a continuous process in many environments and a stratigraphic section may have gaps of significant duration. Also, the magnetic recording process of the rock may be unreliable over all or part of the section. Furthermore, incomplete sampling may give a polarity log that is undersamples. For these reasons, there must be ways of establishing the reliability of a given polarity sequence and the robustness of a given correlation. For a more complete discussion of the subject of magnetostratigraphy, the reader is referred to the comprehensive book by Opdyke and Channell (1996) entitled Magnetic Stratigraphy. Briefly, the elements of a good magnetostratigraphic study include the following points.

15.4.2 Measuring rates

One very useful application of the GPTS is to infer rates of for example spreading, sediment accumulation, etc. We illustrate this approach in Figure 15.10. Distance from the ridge crest of each identified anomaly is plotted against age. The previous standard GPTS based on the work of Cande and Kent (1992) built smooth changes in spreading rate into the GPTS itself. The Gradstein et al. (2004) time scale does not have this constraint for the Neogene, because much of it was calibrated using astrochronological methods. As a result there are sharp changes in spreading rate implied, which may be artifacts of the method of calibration. It may therefore be preferable to calibrate the time scale using some balance between astrochronology, smooth variations in spreading rate and radioisotopic methods.

15.4.3 Tracing of magnetic isochrons

Most magnetostratigraphic applications involve determination of a magnetostratigraphy through a stratigraphic sequence of sediments. Because polarity transitions occur relatively rapidly, the horizon bounding two polarity zones may represent an almost isochronous level. It is therefore possible to use magnetostratigraphy in a lateral sense, in order to delineate isochronous horizons within a given package of sediments (Behrensmeyer and Tauxe. 1982). In Figure ??, we show the application of magnetostratigraphy for tracing isochrons in a series of stratigraphic sections. The small sand body (darker gray) labeled “A” appears to have removed the normal polarity zone seen in sequences on the right of the figure either by erosion or because of unsuitable paleomagnetic properties of sand. Sand bodies B and C appear to represent quasi-isochronous horizons.


Appendix
Table A1: Geomagnetic polarity time scale of Gradstein et al. (2004).





Chron sub-Chron Dist. of old end Age of base (Ma) alternate names





from SA ridge (km)
C1 C1n 12.14 0.781 Brunhes
C1r.1 15.37 0.988 Matuyama
C1r.1n 16.39 1.072 Jaramillo
C1r.3r 27.8 1.778
C2 C2n 31.51 1.945 Olduvai
C2r.1r 35.04 2.128
C2r.1n 35.57 2.1482 Reunion
C2r.2r 41.75 2.581
C2A C2An.1n 49.44 3.032 Gauss
C2An.1r 50.7 3.116 Kaena
C2An.2n 52.31 3.207
C2An.2r 54.1 3.33 Mammoth
C2An.3n 58.03 3.596
C2Ar 66.44 4.187 Gilbert
C3 C3n.1n 68.23 4.3
C3n.1r 70.56 4.493
Cn.2n 73.56 4.631
C3n.2r 76.76 4.799
C3n.3n 78.26 4.896
C3n.3r 80.4 4.997
C3n.4n 84.68 5.235
C3r 86.87 6.033
C3A C3An.1n 101.42 6.252
C3An.1r 103.92 6.436
C3An.2n 109.6 6.733
C3Ar 116.7 7.14
C3B C3Bn 119.74 7.212
C3Br.1r 120.62 7.251
C3Br.1n 121.3 7.285
C3Br.2r 124.68 7.454
C3Br.2n 125.35 7.489
C3Br.3r 126.48 7.528
C4 C4n.1n 129.08 7.642
C4n.1r 130.83 7.695
C4n.2n 139.37 8.108
C4r.1r 142.49 8.254
C4r.1n 143.15 8.3
C4r.2r 152.32 8.769












Chron sub-Chron Dist. of old end Age of base (Ma)





C4A C4An 159.16 9.098
C4Ar.1r 163.49 9.312
C4Ar.1n 165.16 9.409
C4Ar.2r 171 9.656
C4Ar.2n 172.34 9.717
C4A.3r 174.47 9.779
C5 C5n.1n 177.49 9.934
C5n.1r 178.38 9.987
C5n.2n 201.13 11.04
C5r.1r 203.44 11.118
C5r.1n 204.51 11.154
C5r.2r 213.04 11.554
C5r.2n 214.28 12
C5r.3r 223.52 12.014
C5A C5An.1n 226.81 12.116
C5An.1r 229.23 12.207
C5An.2n 234.25 12.415
C5Ar.1r 240.65 12.73
C5Ar.1n 241.35 12.765
C5Ar.2r 242.9 12.82
C5Ar.2n 243.94 12.878
C5Ar.3r 247.92 13.015
C5AA C5AAn 251.38 13.183
C5AAr 255.19 13.369
C5AB C5ABn 260.03 13.605
C5ABr 264.53 13.734
C5AC C5ACn 273.28 14.095
C5ACr 275.66 14.194
C5AD C5ADn 285.8 14.581
C5ADr 290.17 14.784
C5B C5Bn.1n 292.24 14.877
C5Bn.1r 295.63 15.032
C5Bn.2n 298.45 15.16
C5Br 318.39 15.974
C5C C5Cn.1n 324.87 16.268
C5Cn.1r 325.65 16.303
C5Cn.2n 329.38 16.472
C5Cn.2r 330.95 16.543
C5Cn.3n 334.88 16.721
C5Cr 347.64 17.235












Chron sub-Chron Dist. of old end Age of base (Ma)





C5D C5Dn 355.45 17.533
C5Dr 360.88 17.717
C5Dr.1n 361.55 17.74
C5Dr.2r 370.87 18.056
C5E C5En 382.45 18.524
C5Er 388.64 18.748
C6 C6n 413.88 20
C6r 422.93 20.04
C6A C6An.1n 427.81 20.213
C6An.1r 434.18 20.439
C6An.2n 441.85 20.709
C6Ar 452.46 21.083
C6AA C6AAn 454.63 21.159
C6AAr.1r 461.59 21.403
C6AAr.1n 463.92 21.483
C6AAr.1n 468.97 21.659
C6AAr.2r 469.79 21.688
C6AAr.2n 472.08 21.767
C6AAr.3r 475.99 21.936
C6B C6Bn.1n 477.29 21.992
C6Bn.2n 483.7 22.268
C6Br 490.61 22.564
C6C C6Cn.1n 495.05 22.754
C6Cn.1r 498.54 22.902
C6Cn.2n 501.55 23.03
C6Cn.2r 506.47 23.249
C6Cn.3n 509.41 23.375
C6Cr 524.64 24.044
C7 C7n.1n 525.92 24.102
C7n.1r 527.29 24.163
C7n.2n 536.04 24.556
C7r 543.97 24.915
C7A C7An 547.82 25.091
C7Ar 552.3 25.295
C8 C8n.1n 555.55 25.444
C8n.1r 556.6 25.492
C8n.2n 571.04 26.154
C8r 583.3 26.714












Chron sub-Chron Dist. of old end Age of base (Ma)





C9 C9n 607.96 27.826
C9 r 616.12 28.186
C10 C10n.1n 622.16 28.45
C10n.1r 623.9 28.525
C10n.2n 628.29 28.715
C10r 645.65 29.451
C11 C11n.1n 652.56 29.74
C11n.1r 655.31 29.853
C11n.2n 664.15 30.217
C11r 674.26 30.627
C12 C12n 686.5 31.116
C12r 742.63 33.266
C13 C13n 755.44 33.738
C13r 784.4 34.782
C15 C15n 791.78 35.043
C15r 802.15 35.404
C16 C16n.1n 806.87 35.567
C16n.1r 810.93 35.707
C16n.2n 827.67 36.276
C16r 834.68 36.512
C17 C17n.1n 856.19 37.235
C17n.1r 859.46 37.345
C17n.2n 865.54 37.549
C17n.2r 867.33 37.61
C17n.3n 872.1 37.771
C17r 879.83 38.032
C18 C18n.1n 907.31 38.975
C18n.1r 909.21 39.041
C18n.2n 921.21 39.464
C18r 947.96 40.439
C19 C19n 954.12 40.671
C19r 977.65 41.59
C20 C20n 1006.06 42.774
C20r 1060.24 45.346












Chron sub-Chron Dist. of old end Age of base (Ma)





C21 C21n 1094.71 47.235
C21r 1117.55 48.599
C22 C22n 1130.78 49.427
C22r 1150.83 50.73
C23 C23n.1n 1153.9 50.932
C23n.1r 1155.75 51.057
C23n.2n 1168.2 51.901
C23r 1178.96 52.648
C24 C24n.1n 1184.03 53.004
C24n.1r 1185.61 53.116
C24n.2n 1186.34 53.167
C24n.2r 1188.05 53.286
C24n.3n 1195.35 53.808
C24r 1234.51 56.665
C25 C25n 1241.5 57.18
C25r 1257.81 58.379
C26 C26n 1262.74 58.737
C26r 1303.81 61.65
C27 C27n 1308.7 61.983
C27r 1325.71 63.104
C28 C28n 1341.99 64.128
C28r 1347.03 64.432
C29 C29n 1358.66 65.118
C29r 1371.84 65.861
C30 C30n 1407.22 67.696
C30r 1409.56 67.809
C31 C31n 1429.14 68.732
C31r 1481.12 70.961
C32 C32n.1n 1487.68 71.225
C32n.1r 1493.94 71.474
C32n.2n 1531.81 72.929
C32r.1r 1539.94 73.231
C32r.1n 1542.32 73.318
C32r.2r 1549.41 73.577
C33 C33n 1723.76 79.543
C33r 1862.32 84
CNS C34n 125.0






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