EarthRef.org Reference Database (ERR) -- Vervoort & Blichert-Toft 1999

The covariant behavior of Lu-Hf and Sm-Nd isotopes during most magmatic processes has long been recognized, but the: details of this behavior in the depleted mantle reservoir have not been adequately examined. We report new whole-rock Hf and Nd isotope data for 1) juvenile, mantle-derived rocks, mid-Archean to Mesozoic in age, and 2) early Archean gneisses from West Greenland. Hf and Nd isotopic compositions of the juvenile rocks are well correlated, with the best fit corresponding to the equation epsilon(Hf) = 1.40 epsilon(Nd) + 2.1, and is similar to the collective Hf-Nd correlation for terrestrial samples of epsilon(Hf) = 1.36 epsilon(Nd) + 3.0. The early Archean Greenland gneisses, in contrast, have an extreme range in epsilon(Nd) values ((-)4.4 to (+)14.2; Bennett et al., 1993) that is not mirrored by the Hf isotopic system. The epsilon(Hf) values for these rocks are consistently positive and have much less variation (0 to (+)3.4) than their epsilon(Nd) counterparts. The information from the Hf isotopic compositions of the West Greenland gneisses portrays an early Archean mantle that is relatively isotopically homogeneous at 3.8 to 3.6 Ga and moderately depleted in incompatible elements. There is no evidence that any of these gneisses have been derived from an enriched reservoir. The Hf isotopic data an in stark contrast to the Nd isotopic record and strongly imply that the picture of extreme initial isotopic heterogeneity indicated by Nd isotopes is not a real feature of the West Greenland gneisses but is rather an artifact produced by disturbances in the Sm-Nd isotope system of these rocks. Although Hf and Nd isotopic data do not uniquely constrain either the nature of the earliest crust or the timing of crustal growth, the most probable candidate for the enriched reservoir complementary to the depleted mantle in the pre-4.0 Ga Earth is a mafic, oceanic-type crust. In order to explain the predominantly positive epsilon(Hf) and epsilon(Nd) values for the early Archean rocks, this crust must have had a short residence time at the surface of the Earth before returning to the mantle where it was isolated from mixing with the depleted mantle for several hundred millon years. The following period from 3.5 to 2.7 Ga may mark a transition during which this early formed mafic crust was mixed progressively back into the depleted mantle reservoir. While a present-day volume of continental crust at 3.0 Ga cannot be excluded on isotopic grounds, we find such a scenario unlikely based on the lack of direct isotopic and physical evidence for its existence. An important aspect of crustal growth and evolution, therefore, may be the transformation of the enriched reservoir from being predominantly mafic in the early Earth to becoming progressively more sialic through time. Copyright (C) 1999 Elsevier Science Ltd.