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Liu et al. 1988
Liu, X., Wang, Y. and Liebermann, R.C. (1988). Orthorhombic-tetragonal phase transition in CaGeO3 perovskite at high temperature. Geophysical Research Letters 15: doi: 10.1029/88GL03462. issn: 0094-8276.

CaGeO3 perovskite was synthesized from its wollastonite polymorph at P=8 Gap and T=1000¿C in a uniaxial split-sphere apparatus (USSA-2000). For recovered specimens heated to less than 500¿C at 1 bar, the crystallographic distortion of the orthorhombic (Pbnm) CaGeO3 perovskite, that is the tilting of the [GeO6> octahedra, decreases with increasing temperature in the range 25--250¿C. At temperatures near 250¿C, CaGeO3 undergoes a reversible transformation from an orthorhombic to a tetragonal structure, accompanied by an abrupt increase in the mean thermal expansion. Such behavior is typical of other orthorhombic perovskites and may occur for silicate perovskites in the lower mantle. ¿ American Geophysical Union 1988

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Abstract

Keywords
Mineral Physics, Physical thermodynamics
Journal
Geophysical Research Letters
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Publisher
American Geophysical Union
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