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Detailed Reference Information |
Marti, J., Mauersberger, K. and Hanson, D. (1991). HCL dissolved in solid mixtures of nitric acid and ice: Implications for the polar stratosphere. Geophysical Research Letters 18: doi: 10.1029/91GL02313. issn: 0094-8276. |
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The solubility of HCl in polar stratospheric cloud (PSC) particles plays an important role in the heterogeneous chemistry of the lower polar stratosphere. New labortory studies are reported showing a strong dependence of the HCl solubility on the HNO3 content in ice particles. At 200 K and a partial HCl pressure of 10-6 Torr, the HCl content in NAT is 0.35 mol%, decreasing about a factor of 3 for every 10 fold decrease in the substrate's HNO3 content. At an HCl pressure of 10-7 Torr the content is about 40% of that at 10-6 Torr. HCl dissolved in pure water ice at these partial pressures is less than 0.002 mol%. The surface coverage of HCl on small ice samples was estimated to be about 0.1 monolayer at 10-6 Torr exposure. ¿American Geophysical Union 1991 |
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Abstract |
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Keywords
Atmospheric Composition and Structure, Middle atmosphere—composition and chemistry, Atmospheric Composition and Structure, Cloud physics and chemistry |
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Publisher
American Geophysical Union 2000 Florida Avenue N.W. Washington, D.C. 20009-1277 USA 1-202-462-6900 1-202-328-0566 service@agu.org |
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