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Detailed Reference Information |
Chance, K.V., Johnson, D.G., Traub, W.A. and Jucks, K.W. (1991). Measurement of the stratospheric hydrogen peroxide concentration profile using far infrared thermal emission spectroscopy. Geophysical Research Letters 18: doi: 10.1029/91GL01224. issn: 0094-8276. |
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We have made the first unequivocal measurement of hydrogen peroxide in the stratosphere, a concentration profile obtained from a balloon platform using Fourier transform thermal emission spectroscopy in the far infrared. Measurements were made using the 112 cm-1 RQ5 branch of the rotational-torsional spectrum, with some confirmation from the 94 cm-1 RQ4 branch. The atmospheric spectra were obtained from a balloon flight on September 26--27, 1989, launched from Fort Sumner, NM. The volume mixing ratio of H2O2 is 1.6¿10-10 at 38.4 km, decreasing to 0.6¿10-10 at 23.8 km, with uncertainties of about 16% (1&sgr;). Our measurements are compared to a recent stratospheric model calculation. |
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Abstract |
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Keywords
Atmospheric Composition and Structure, Middle atmosphere—composition and chemistry, Atmospheric Composition and Structure, Instruments and techniques |
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Publisher
American Geophysical Union 2000 Florida Avenue N.W. Washington, D.C. 20009-1277 USA 1-202-462-6900 1-202-328-0566 service@agu.org |
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