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Detailed Reference Information |
Mellouki, A., Talukdar, R.K., Schmoltner, A., Gierczak, T., Mills, M.J., Solomon, S. and Ravishankara, A.R. (1992). Atmospheric lifetimes and ozone depletion potentials of methyl bromide (CH3Br) and dibromomethane (CH2Br2). Geophysical Research Letters 19: doi: 10.1029/92GL01612. issn: 0094-8276. |
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The rate coefficients for the reactions of OH radical with CH3Br and CH2Br2 were measured as functions of temperature using the laser photolysis-laser induced fluorescence method. This data was incorporated into a semi-empirical model [Solomon et al., 1992> and a 2-D model to calculate the steady-state Ozone Depletion Potentials (ODP) and atmospheric lifetimes, &tgr;, with greatly improved accuracy as compared to earlier studies. The calculated ODPs and &tgr; are 0.65 and 1.7 years and 0.17 and 0.41 years for CH3Br and CH2Br2, respectively, using the semi-empirical model. These lifetimes agree well with those calculated using a 2-D model. This study better quantifies the ODPs and &tgr; of these species which are needed inputs for discussion of possible regulation of human emissions currently under international considerations. ¿ American Geophysical Union 1992 |
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Abstract |
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Keywords
Atmospheric Composition and Structure, Troposphere—composition and chemistry |
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Publisher
American Geophysical Union 2000 Florida Avenue N.W. Washington, D.C. 20009-1277 USA 1-202-462-6900 1-202-328-0566 service@agu.org |
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