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Mellouki et al. 1992
Mellouki, A., Talukdar, R.K., Schmoltner, A., Gierczak, T., Mills, M.J., Solomon, S. and Ravishankara, A.R. (1992). Atmospheric lifetimes and ozone depletion potentials of methyl bromide (CH3Br) and dibromomethane (CH2Br2). Geophysical Research Letters 19: doi: 10.1029/92GL01612. issn: 0094-8276.

The rate coefficients for the reactions of OH radical with CH3Br and CH2Br2 were measured as functions of temperature using the laser photolysis-laser induced fluorescence method. This data was incorporated into a semi-empirical model [Solomon et al., 1992> and a 2-D model to calculate the steady-state Ozone Depletion Potentials (ODP) and atmospheric lifetimes, &tgr;, with greatly improved accuracy as compared to earlier studies. The calculated ODPs and &tgr; are 0.65 and 1.7 years and 0.17 and 0.41 years for CH3Br and CH2Br2, respectively, using the semi-empirical model. These lifetimes agree well with those calculated using a 2-D model. This study better quantifies the ODPs and &tgr; of these species which are needed inputs for discussion of possible regulation of human emissions currently under international considerations. ¿ American Geophysical Union 1992

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Abstract

Keywords
Atmospheric Composition and Structure, Troposphere—composition and chemistry
Journal
Geophysical Research Letters
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Publisher
American Geophysical Union
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