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Chandra et al. 1993
Chandra, S., Jackman, C.H., Douglass, A.R., Fleming, E.L. and Considine, D.B. (1993). Chlorine catalyzed destruction of ozone: Implications for ozone variability in the upper stratosphere. Geophysical Research Letters 20: doi: 10.1029/93GL00212. issn: 0094-8276.

The annual mean and the annual amplitude of ozone have been derived from ozone measurements from the SBUV and SBUV/2 spectrometers on board the Nimbus-7 and NOAA-11 satellites. These values differ significantly from values calculated using a two-dimensional model of stratospheric photochemistry and dynamics with standard chemistry. We have found that the differences between the calculated and data-derived values are considerably improved by changing the partitioning in the Cly family to create a larger reservoir of HCl and reducing ClO. This is accomplished by including a channel for the products HCl+O2 from the reaction ClO+OH in addition to the products Cl+HO2. This partitioning also improves the agreement between the calculated and measured values of ClO/HCl ratio. ¿ American Geophysical Union 1993

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Abstract

Keywords
Atmospheric Composition and Structure, Middle atmosphere—composition and chemistry
Journal
Geophysical Research Letters
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Publisher
American Geophysical Union
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