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Detailed Reference Information |
Müller, R., Peter, T., Crutzen, P.J., Oelhaf, H., Adrian, G.P., Clarmann, T. v., Wegner, A., Schmidt, U. and Lary, D. (1994). Chlorine chemistry and the potential for ozone depletion in the Arctic stratosphere in the winter of 1991/92. Geophysical Research Letters 21: doi: 10.1029/94GL00465. issn: 0094-8276. |
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We present an analysis of chlorine chemistry in the Arctic stratosphere during the winter of 1991/92 and assess its potential implications for ozone depletion. In accordance with observations of total organic chlorine, ClONO2 and HCl, box model results indicate the following: (1) An almost complete activation of chlorine during the cold winter period. (2) A possible contribution from the heterogeneous reaction HOCl+HCl and the gas-phase reaction CH3O2+ClO to the complete conversion of HCl to active chlorine. (3) A strong buildup of ClONO2 following PSC disappearance which remains the main chlorine reservoir for about a month, after which HCl becomes dominant. (4) Appreciable chemical ozone loss in the lower stratosphere inside the polar vortex is conceivable for the winter of 1991/92 ¿American Geophysical Union 1994 |
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Abstract |
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Keywords
Atmospheric Composition and Structure, Middle atmosphere—composition and chemistry, Atmospheric Composition and Structure, Aerosols and particles |
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Publisher
American Geophysical Union 2000 Florida Avenue N.W. Washington, D.C. 20009-1277 USA 1-202-462-6900 1-202-328-0566 service@agu.org |
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