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Müller et al. 1994
Müller, R., Peter, T., Crutzen, P.J., Oelhaf, H., Adrian, G.P., Clarmann, T. v., Wegner, A., Schmidt, U. and Lary, D. (1994). Chlorine chemistry and the potential for ozone depletion in the Arctic stratosphere in the winter of 1991/92. Geophysical Research Letters 21: doi: 10.1029/94GL00465. issn: 0094-8276.

We present an analysis of chlorine chemistry in the Arctic stratosphere during the winter of 1991/92 and assess its potential implications for ozone depletion. In accordance with observations of total organic chlorine, ClONO2 and HCl, box model results indicate the following: (1) An almost complete activation of chlorine during the cold winter period. (2) A possible contribution from the heterogeneous reaction HOCl+HCl and the gas-phase reaction CH3O2+ClO to the complete conversion of HCl to active chlorine. (3) A strong buildup of ClONO2 following PSC disappearance which remains the main chlorine reservoir for about a month, after which HCl becomes dominant. (4) Appreciable chemical ozone loss in the lower stratosphere inside the polar vortex is conceivable for the winter of 1991/92 ¿American Geophysical Union 1994

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Abstract

Keywords
Atmospheric Composition and Structure, Middle atmosphere—composition and chemistry, Atmospheric Composition and Structure, Aerosols and particles
Journal
Geophysical Research Letters
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Publisher
American Geophysical Union
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