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| Detailed Reference Information |
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Irion, F.W., Brown, M., Toon, G.C. and Gunson, M.R. (1994). Increase in atmospheric CHF2Cl (HCFC-22) over southern California from 1985 to 1990. Geophysical Research Letters 21: doi: 10.1029/94GL01323. issn: 0094-8276. |
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Column densities of CHF2Cl (HCFC-22) have been measured over Table Mountain Facility (TMF), Wrightwood, California (34.4¿N) using the Atmospheric Trace Molecule Spectroscopy (ATMOS) Fourier-transform infrared (FTIR) spectrometer. Between October 1985 and July 1990, the exponential column increase rate was (6.5¿0.5)% yr-1. Additionally, column measurements of CHF2Cl over McMurdo Sound, Antarctica (78¿S) in September and October 1986 by the MarkIV FTIR spectrometer were used to derive a south-north interhemispheric ratio of (0.86¿0.08). Model calculations investigated the feasibility of using CHF2Cl column measurements with a predicted global OH field to determine a globally averaged chemical lifetime for CHF2Cl, or equivalently, an estimate of the OH field using a predicted lifetime. The current uncertainty in historical CHF2Cl emissions is too large for CHF2Cl to be used to infer adequately either the lifetime or the OH field. ¿ American Geophysical Union 1994 |
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Abstract |
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Keywords
Atmospheric Composition and Structure, Evolution of the atmosphere, Atmospheric Composition and Structure, Troposphere—composition and chemistry |
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Publisher
American Geophysical Union 2000 Florida Avenue N.W. Washington, D.C. 20009-1277 USA 1-202-462-6900 1-202-328-0566 service@agu.org |
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