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Chen & Ahrens 1995
Chen, G. and Ahrens, T.J. (1995). Equations of state of a, ¿ and liquid iron and Iron's melting curve—thermodynamic calculations. Geophysical Research Letters 22: doi: 10.1029/94GL02892. issn: 0094-8276.

The melting curve between &egr; and liquid iron (100GPa<P<300GPa) has been derived by computing Gibbs free energies at high pressures and high temperatures from equations of state of the &agr;, &egr; and liquid phases. The most uncertainty lies in the equation of state (EOS) of the &egr; phase. By comparing the calculations to experimental data, the internal thermodynamic consistency of the three phases are examined. The best fits to the melting curves of Boehler [1993> and Williams et al. [1987> can be obtained with lower bulk moduli than determined by static compression. Using available equations of state of the iron phases, our calculations indicate that if sub-solidus iron is of the &egr;, phase, Boehler's melting curve is thermodynamically more consistent than Williams et al.'s. The problem is complicated by the possible existence of a new phase between the &egr; and the liquid fields. ¿ American Geophysical Union 1995

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Abstract

Keywords
Mineral Physics, Equations of state, Mineral Physics, High-pressure behavior, Mineral Physics, Physical thermodynamics
Journal
Geophysical Research Letters
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Publisher
American Geophysical Union
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