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Detailed Reference Information |
Hauglustaine, D.A., Ridley, B.A., Solomon, S., Hess, P.G. and Madronich, S. (1996). HNO3/NOx ratio in the remote troposphere During MLOPEX 2: Evidence for nitric acid reduction on carbonaceous aerosols?. Geophysical Research Letters 23: doi: 10.1029/96GL02474. issn: 0094-8276. |
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The [HNO3>/[NOx> ratio is generally overestimated by a factor of 5--10 in photochemical models in comparison to tropospheric measurements. In this study the heterogeneous reduction of HNO3 into NO on carbonaceous aerosols [Lary et al., 1996> has been introduced in a photochemical box-model on the basis of black carbon mass densities measured during MLOPEX 2. This recycling to NOx decreases the [HNO3>/[NOx> ratio close to observed values. The concomitant increase in modeled NOx concentration is also in better agreement with the observations, and has substantial implications for the ozone budget in the remote atmosphere. Large uncertainties in the estimate of black carbon surface area and of accommodation coefficients preclude definitive conclusions until more detailed measurements are carried out. ¿ American Geophysical Union 1996 |
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Abstract |
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Keywords
Atmospheric Composition and Structure, Troposphere—composition and chemistry, Atmospheric Composition and Structure, Aerosols and particles (0345, 4801) |
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Publisher
American Geophysical Union 2000 Florida Avenue N.W. Washington, D.C. 20009-1277 USA 1-202-462-6900 1-202-328-0566 service@agu.org |
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