EarthRef.org Reference Database (ERR)
Development and Maintenance by the EarthRef.org Database Team

Detailed Reference Information
Danilin et al. 1996
Danilin, M.Y., Sze, N., Ko, M.K.W., Rodriguez, J.M. and Prather, M.J. (1996). Bromine-chlorine coupling in the Antarctic Ozone Hole. Geophysical Research Letters 23: doi: 10.1029/95GL03783. issn: 0094-8276.

The contribution from the chlorine and bromine species in the formation of the Antarctic ozone hole is evaluated. Since chlorine and bromine compounds are of different industrial origin, it is desirable, from a policy point of view, to be able to attribute chlorine-catalyzed loss of ozone with those reactions directly involving chlorine species, and likewise for bromine-catalyzed loss. In the stratosphere, however, most of the chemical families are highly coupled, and, for example, changes in the chlorine abundance will alter the partitioning in other families and thus the rate of ozone loss. This modeling study examines formation of the Antarctic ozone hole for a wide range of bromine concentrations (5--25 pptv) and for chlorine concentrations typical of the last two decades (1.5, 2.5 and 3.5 ppbv). We follow the photochemical evolution of a single parcel of air, typical of the inner Antarctic vortex (50 mbar, 70¿S, NOy=2 ppbv, with polar stratospheric clouds(PSC)) from August 1 to November 1. For all of these ranges of chlorine and bromine loading, we would predict a substantial ozone hole (local depletion greater than 90%) within the de-nitrified, PSC-perturbed vortex. The contributions of the different catalytic cycles responsible for ozone loss are tabulated. The deep minimum in ozone is driven primarily by the chlorine abundance. As bromine levels decrease, the magnitude of the chlorine-catalyzed ozone loss increases to take up the slack. This is because bromine suppresses CIO by accelerating the conversion of CIO and Cl2O2 back to HCl. For this range of conditions, the local relative efficiency of ozone destruction per bromine atom to that per chlorine atom (&agr;-factor) ranges from 33 to 55, decreasing with increase of bromine. ¿ American Geophysical Union 1996

BACKGROUND DATA FILES

Abstract

Keywords
Oceanography, Biological and Chemical, Aerosols
Journal
Geophysical Research Letters
http://www.agu.org/journals/gl/
Publisher
American Geophysical Union
2000 Florida Avenue N.W.
Washington, D.C. 20009-1277
USA
1-202-462-6900
1-202-328-0566
service@agu.org
Click to clear formClick to return to previous pageClick to submit