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Moyer et al. 1996
Moyer, E.J., Irion, F.W., Yung, Y.L. and Gunson, M.R. (1996). ATMOS stratospheric deuterated water and implications for troposphere-stratosphere transport. Geophysical Research Letters 23: doi: 10.1029/96GL01489. issn: 0094-8276.

Measurements of the isotopic composition of stratospheric water by the ATMOS instrument are used to infer the convective history of stratospheric air. The average water vapor entering the stratosphere is found to be highly depleted of deuterium, with ΔDw of -670¿80 (67% deuterium loss). Model calculations predict, however, that under conditions of thermodynamic equilibrium, dehydration to stratospheric mixing ratios should produce stronger depletion to ΔDw of -800 to -900 (80--90% deuterium loss). Deuterium enrichment of water vapor in ascending parcels can occur only in conditions of rapid convection; enrichments persisting into the stratosphere require that those conditions continue to near-tropopause altitudes. We conclude that either the predominant source of water vapor to the uppermost troposphere is enriched convective water, most likely evaporated cloud ice, or troposphere-stratosphere transport occurs closely associated with tropical deep convection. ¿ American Geophysical Union 1996

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Abstract

Keywords
Atmospheric Composition and Structure, Cloud physics and chemistry, Atmospheric Composition and Structure, Troposphere—constituent transport and chemistry
Journal
Geophysical Research Letters
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Publisher
American Geophysical Union
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