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Detailed Reference Information |
Hanson, D.R. (1997). Reaction of N2O5 with H2O on bulk liquids and on particles and the effect of dissolved HNO3. Geophysical Research Letters 24: doi: 10.1029/97GL00917. issn: 0094-8276. |
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Measurements of the reaction probability (&ggr;) of N2O3 on ~60 wt % H2SO4 were performed at 201 to 230 K on bulk liquids and at 230 K on aerosol particles. The bulk and aerosol results are in good agreement (less than 10% difference). The measurements on bulk liquids show very little change in &ggr; with temperature from 201 to 230 K. HNO3 was added to the bulk liquids at ~201 K and to aerosol particles at 230 K (the H2SO4-content was decreased to keep water activity approximately constant). For [HNO3> levels of 1-to-15 wt %, the N2O5 reaction probability decreased by ~15 % from that measured on HNO3-free 60 wt % H2SO4. For 60 wt % H2SO4 aerosol in the stratosphere ([HNO3>~0.3 wt %) the decrease in the N2O5 hydrolysis reaction probability due to HNO3 would be small.¿ 1997 American Geophysical Union |
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Abstract |
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Keywords
Atmospheric Composition and Structure, Middle atmosphere—composition and chemistry, Atmospheric Composition and Structure, Aerosols and particles (0345, 4801), Atmospheric Composition and Structure, Cloud physics and chemistry |
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Publisher
American Geophysical Union 2000 Florida Avenue N.W. Washington, D.C. 20009-1277 USA 1-202-462-6900 1-202-328-0566 service@agu.org |
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