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Hanson 1997
Hanson, D.R. (1997). Reaction of N2O5 with H2O on bulk liquids and on particles and the effect of dissolved HNO3. Geophysical Research Letters 24: doi: 10.1029/97GL00917. issn: 0094-8276.

Measurements of the reaction probability (&ggr;) of N2O3 on ~60 wt % H2SO4 were performed at 201 to 230 K on bulk liquids and at 230 K on aerosol particles. The bulk and aerosol results are in good agreement (less than 10% difference). The measurements on bulk liquids show very little change in &ggr; with temperature from 201 to 230 K. HNO3 was added to the bulk liquids at ~201 K and to aerosol particles at 230 K (the H2SO4-content was decreased to keep water activity approximately constant). For [HNO3> levels of 1-to-15 wt %, the N2O5 reaction probability decreased by ~15 % from that measured on HNO3-free 60 wt % H2SO4. For 60 wt % H2SO4 aerosol in the stratosphere ([HNO3>~0.3 wt %) the decrease in the N2O5 hydrolysis reaction probability due to HNO3 would be small.¿ 1997 American Geophysical Union

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Keywords
Atmospheric Composition and Structure, Middle atmosphere—composition and chemistry, Atmospheric Composition and Structure, Aerosols and particles (0345, 4801), Atmospheric Composition and Structure, Cloud physics and chemistry
Journal
Geophysical Research Letters
http://www.agu.org/journals/gl/
Publisher
American Geophysical Union
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