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Mauldin et al. 1997
Mauldin, R.L., Madronich, S., Flocke, S.J., Eisele, F.L., Frost, G.J. and Prevot, A.S.H. (1997). New insights on OH: Measurements around and in clouds. Geophysical Research Letters 24: doi: 10.1029/97GL02983. issn: 0094-8276.

The first airborne measurements of OH performed in the lower free troposphere are presented. Measurements performed above clouds yielded large [OH>, with values of 8--15¿106 molecule cm-3, compared with values of 3--5¿106 molecule cm-3 measured in cloud free regions. Measurements performed inside a cloud also yielded relatively high [OH>, with values of 7.5¿106 molecule cm-3, yet a factor of 2 lower than 15¿106 molecule cm-3 measured just above the cloud. Steady state model calculations using Eppley scaled photolysis rates underestimate [OH> above clouds and overestimate [OH> inside clouds. Actinic fluxes of 2.5 times clear sky values (obtained from theoretical calculations) bring model values into agreement with those measured above clouds, while OH loss onto cloud droplets needs to be included for calculations inside clouds. ¿ 1997 American Geophysical Union

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Abstract

Keywords
Atmospheric Composition and Structure, Chemical kinetic and photochemical properties, Atmospheric Composition and Structure, Cloud physics and chemistry, Atmospheric Composition and Structure, Transmission and scattering of radiation
Journal
Geophysical Research Letters
http://www.agu.org/journals/gl/
Publisher
American Geophysical Union
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