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Chartrand & McConnell 1998
Chartrand, D.J. and McConnell, J.C. (1998). Evidence for HBr production due to minor channel branching at mid-latitudes. Geophysical Research Letters 25: doi: 10.1029/97GL03355. issn: 0094-8276.

Recently, Nolt et al. [1997> have presented HBr measurements over the height range 20--36 km. We have compared model calculations with these measurements and find definitive evidence for non-zero branching ratios for HBr production from either HO2+BrO, k1b, or OH+BrO, k2b. For k1b, best agreement between modelled and observed HBr concentrations is obtained if the branching ratio increases from ~0.4% at 20 km, to about 2% at 34 km with no additional contribution from the OH+BrO branch. However, a height-independent value of 1% also produces reasonable results. This branching ratio contradicts the study of Mellouki et al. [1994>. For OH+BrO, the best value of k2b appears to be 2--3%, if k1a=0 which is comparable to the recently determined branching ratio for HCl production from the analogous chlorine reaction, OH+ClO. ¿ 1998 American Geophysical Union

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Abstract

Keywords
Atmospheric Composition and Structure, Middle atmosphere—composition and chemistry
Journal
Geophysical Research Letters
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Publisher
American Geophysical Union
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