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Gupta et al. 1998
Gupta, M.L., Cicerone, R.J. and Elliott, S. (1998). Perturbation to global tropospheric oxidizing capacity due to latitudinal redistribution of surface sources of NOx, CH4 and CO. Geophysical Research Letters 25: doi: 10.1029/1998GL900099. issn: 0094-8276.

Economic and social projections indicate that during next several decades there will be major geographical redistribution of surface emissions of O3 precursors, such as NOx, CH4 and CO. A net decrease in their emissions from northern hemispheric mid-latitudes will be accompanied by substantial increases from the tropics. We have investigated a hypothetical scenario of currently underway transition of such emission patterns using a global two-dimensional photo-chemical model. With overall O3 precursor releases held constant, a simultaneous transfer of their emissions by 25% from the latitude belt 75 ¿N--35 ¿N to 5 ¿S--35 ¿N increases tropospheric oxidizing capacity such that the methane global lifetime and concentrations fall by more than 3%. Seasonally dependent changes in surface O3 concentrations are also calculated. In influencing OH concentration, redistribution of surface NOx emissions is 2-3 orders of magnitude more efficient per unit mass than CO emissions. Shifts in methane sources have insignificant effects on global photochemistry, but lead to a decrease in its interhemispheric gradient. ¿ 1998 American Geophysical Union

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Abstract

Keywords
Atmospheric Composition and Structure, Troposphere—composition and chemistry, Atmospheric Composition and Structure, Troposphere—constituent transport and chemistry, Atmospheric Composition and Structure, Constituent sources and sinks, Atmospheric Composition and Structure
Journal
Geophysical Research Letters
http://www.agu.org/journals/gl/
Publisher
American Geophysical Union
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