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Sommerfeld et al. 1998
Sommerfeld, R.A., Knight, C.A. and Laird, S.K. (1998). Diffusion of HNO3 in ice. Geophysical Research Letters 25: doi: 10.1029/98GL00413. issn: 0094-8276.

We designed a series of experiments to verify the value of the diffusion coefficient of HNO3 in ice at -15 ¿C using a serial sectioning technique. Our first series of experiments with diffusion times of 70 to 100 h gave an average value of about 1.7¿10-11 cm2 s-1 (StD 0.8¿10-11) and a second set of experiments at 1000 h resulted in an apparent diffusion coefficient of 10-12 cm2 s-1. Our conclusion is that the observed gradients of HNO3 in ice were spurious and the result of serial contamination of the surfaces during sectioning of the ice. We call the diffusion coefficients apparent because in the present experiment we could not distinguish between an undetectable diffusion coefficient and undetectable solubility. In either case, the validity of the previously published results is questionable. ¿ 1998 American Geophysical Union

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Abstract

Keywords
Hydrology, Glaciology, Hydrology, Snow and ice, Atmospheric Composition and Structure, Troposphere—composition and chemistry
Journal
Geophysical Research Letters
http://www.agu.org/journals/gl/
Publisher
American Geophysical Union
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