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Michelsen et al. 1999
Michelsen, H.A., Spivakovsky, C.M. and Wofsy, S.C. (1999). Aerosol-Mediated Partitioning of Stratospheric Cly and NOy at Temperatures Above 200 K. Geophysical Research Letters 26: doi: 10.1029/1998GL900281. issn: 0094-8276.

Rates of aerosol-mediated reactions involving inorganic halogen species are small but non-negligible for moderate aerosol abundances at temperatures of 200--210 K. We have used a photochemical model to demonstrate that at these temperatures such reactions provide a significant sink for HCl. Gas-phase production rates are slower for HCl than for ClNO3. The net result is perferential partitioning of Cly into [ClNO3> to compensate for the accelerated loss of [HCl>. Under such conditions, [HNO3> decreases in response to enhanced partitioning of NOy into [ClNO3>. The results indicate a high sensitivity and synergistic response of HCl, ClNO3, and HNO3 distributions to aerosol content and temperature ¿ 1999 American Geophysical Union

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Keywords
Atmospheric Composition and Structure, Atmospheric Composition and Structure, Chemical kinetic and photochemical properties, Atmospheric Composition and Structure, Middle atmosphere—composition and chemistry
Journal
Geophysical Research Letters
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American Geophysical Union
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