EarthRef.org Reference Database (ERR)
Development and Maintenance by the EarthRef.org Database Team

Detailed Reference Information
Tabazadeh et al. 1999
Tabazadeh, A., Toon, O.B. and Jensen, E.J. (1999). A surface chemistry model for nonreactive trace gas adsorption on ice: Implications for nitric acid scavenging by cirrus. Geophysical Research Letters 26: doi: 10.1029/1999GL900501. issn: 0094-8276.

According to recent measurements HNO3 nearly saturates laboratory ice films in flow tubes for vapor pressures above 10-7 torr and temperatures below 230 K. In the upper troposphere the HNO3 vapor pressure is in the range of 1 to 3¿10-8 torr and therefore the current laboratory estimates of saturation may not hold in the atmosphere. Here, with the aid of a surface chemistry model and laboratory data we estimate that the binding energy for HNO3 adsorbed on ice is about -14.2¿0.2 kcal mol-1. Using the surface model, we explore the sensitivity of HNO3 scavenging efficiency to cirrus cloud temperature, ice number density, and HCl competitive coadsorption. ¿ 1999 American Geophysical Union

BACKGROUND DATA FILES

Abstract

Keywords
Atmospheric Composition and Structure, Cloud physics and chemistry, Atmospheric Composition and Structure, Aerosols and particles (0345, 4801), Atmospheric Composition and Structure, Chemical kinetic and photochemical properties, Atmospheric Composition and Structure
Journal
Geophysical Research Letters
http://www.agu.org/journals/gl/
Publisher
American Geophysical Union
2000 Florida Avenue N.W.
Washington, D.C. 20009-1277
USA
1-202-462-6900
1-202-328-0566
service@agu.org
Click to clear formClick to return to previous pageClick to submit