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Detailed Reference Information |
Tabazadeh, A., Toon, O.B. and Jensen, E.J. (1999). A surface chemistry model for nonreactive trace gas adsorption on ice: Implications for nitric acid scavenging by cirrus. Geophysical Research Letters 26: doi: 10.1029/1999GL900501. issn: 0094-8276. |
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According to recent measurements HNO3 nearly saturates laboratory ice films in flow tubes for vapor pressures above 10-7 torr and temperatures below 230 K. In the upper troposphere the HNO3 vapor pressure is in the range of 1 to 3¿10-8 torr and therefore the current laboratory estimates of saturation may not hold in the atmosphere. Here, with the aid of a surface chemistry model and laboratory data we estimate that the binding energy for HNO3 adsorbed on ice is about -14.2¿0.2 kcal mol-1. Using the surface model, we explore the sensitivity of HNO3 scavenging efficiency to cirrus cloud temperature, ice number density, and HCl competitive coadsorption. ¿ 1999 American Geophysical Union |
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Abstract |
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Keywords
Atmospheric Composition and Structure, Cloud physics and chemistry, Atmospheric Composition and Structure, Aerosols and particles (0345, 4801), Atmospheric Composition and Structure, Chemical kinetic and photochemical properties, Atmospheric Composition and Structure |
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Publisher
American Geophysical Union 2000 Florida Avenue N.W. Washington, D.C. 20009-1277 USA 1-202-462-6900 1-202-328-0566 service@agu.org |
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