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Detailed Reference Information |
Portmann, R.W., Brown, S.S., Gierczak, T., Talukdar, R.K., Burkholder, J.B. and Ravishankara, A.R. (1999). Role of nitrogen oxides in the stratosphere: A reevaluation based on laboratory studies. Geophysical Research Letters 26: doi: 10.1029/1999GL900499. issn: 0094-8276. |
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The changes in chemical partitioning and stratospheric O3 abundance due to the recently measured rate coefficients for the O+NO2, OH+HNO3, and OH+NO2 reactions are examined using a two-dimensional model. The rate constant changes increase NOx abundance (up to 40%) and NOx-catalyzed O3 destruction, and extend down by several kilometers the altitude region where NOx dominates catalytic O3 destruction. Reductions in the abundance of HOx (10--30%) and ClOx (20--40%) in the lower stratosphere partially buffer the effect on column O3 amount. Column O3 at middle and high latitudes is reduced by 2--10% depending on season for current halogen levels. The model derived long-term O3 trend at midlatitudes due to increases in anthropogenic halogens is reduced by approximately 30%. ¿ 1999 American Geophysical Union |
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Abstract |
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Keywords
Atmospheric Composition and Structure, Middle atmosphere—composition and chemistry, Atmospheric Composition and Structure, Chemical kinetic and photochemical properties, Atmospheric Composition and Structure |
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Publisher
American Geophysical Union 2000 Florida Avenue N.W. Washington, D.C. 20009-1277 USA 1-202-462-6900 1-202-328-0566 service@agu.org |
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