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Detailed Reference Information |
Fischer, H., Wienhold, F.G., Hoor, P., Bujok, O., Schiller, C., Siegmund, P., Ambaum, M., Scheeren, H.A. and Lelieveld, J. (2000). Tracer correlations in the northern high latitude lowermost stratosphere: Influence of cross-tropopause mass exchange. Geophysical Research Letters 27: doi: 10.1029/1999GL010879. issn: 0094-8276. |
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We present an analysis of trace gas correlations in the lowermost stratosphere. In-situ aircraft measurements of CO, N2O, NOy and O3, obtained during the STREAM 1997 winter campaign, have been used to investigate the role of cross-tropopause mass exchange on tracer-tracer relations. At altitudes several kilometers above the local tropopause, undisturbed stratospheric air was found with NOy/NOy* ratios close to unity, NOy/O3 about 0.003--0.006 and CO mixing ratios as low as 20 ppby (NOy* is a proxy for total reactive nitrogen derived from NOy-N2O relations measured in the stratosphere). Mixing of tropospheric air into the lowermost stratosphere has been identified by enhanced ratios of NOy/NOy* and NOy/O3, and from scatter plots of CO versus O3. The enhanced NOy/O3 ratio in the lowermost stratospheric mixing zone points to a reduced efficiency of O3 formation from aircraft NOx emissions. ¿ 2000 American Geophysical Union |
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Abstract |
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Keywords
Atmospheric Composition and Structure, Meteorology and Atmospheric Dynamics, Stratosphere/troposphere interactions |
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Publisher
American Geophysical Union 2000 Florida Avenue N.W. Washington, D.C. 20009-1277 USA 1-202-462-6900 1-202-328-0566 service@agu.org |
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