Ring effect refers to the 'filling-in' of the Fraunhofer absorption lines in the day sky spectrum as compared to the solar spectrum. Rotational Raman scattering is believed to be the main cause for this excess in the sky spectrum. Earlier measurements showed contradictory behavior of this effect with solar zenith angle and wavelength. It is important to take proper account of this effect as it otherwise results in overestimating the dayglow emission intensities and underestimating the number densities of atmospheric trace gases. The present study details the results obtained from a simultaneous 11-wavelength investigation carried out using a newly built daytime spectrograph. This data demonstrates that the absorption line strength (normalized depth¿half width) has a major control on the Ring effect contribution irrespective of the solar zenith angle and the wavelength. ¿ 2000 American Geophysical Union