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Detailed Reference Information |
Burkholder, J.B., Mills, M. and McKeen, S. (2000). Upper limit for the UV absorption cross sections of H2SO4. Geophysical Research Letters 27: doi: 10.1029/1999GL011271. issn: 0094-8276. |
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An upper limit for the gas phase absorption cross sections for H2SO4 over the wavelength range 195 to 330 nm has been determined. Absorption measurements were made using a diode array spectrometer and a 100 cm long heated absorption cell. Gas phase H2SO4 was generated in a gas flow by titrating (equilibrating) known amounts of SO3 via the reaction SO3+H2O↔H2SO4 at elevated temperatures, ~500 K. Upper limits to the H2SO4 absorption cross sections were obtained, <1¿10-21 cm2 molecule-1, and provide an upper limit to the atmospheric photolysis rate of H2SO4. The implications of this cross section limit to stratospheric sulfur chemistry are discussed. ¿ 2000 American Geophysical Union |
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Abstract |
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Keywords
Atmospheric Composition and Structure, Atmospheric Composition and Structure, Chemical kinetic and photochemical properties, Atmospheric Composition and Structure, Middle atmosphere—composition and chemistry |
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Publisher
American Geophysical Union 2000 Florida Avenue N.W. Washington, D.C. 20009-1277 USA 1-202-462-6900 1-202-328-0566 service@agu.org |
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