Data from the Shuttle Potential and Return Electron Experiment (SPREE) flown as part of the Tethered Satellite System (TSS 1) are used to determine the detailed characteristics of beam arc distributions of pickup ions due to molecules outgassed or ejected from the shuttle. These ion distributions are only detected near the plane perpendicular to the magnetic field direction in an angular range of ¿45¿ about the minimum angle to ram. Their flux is largest when the angle between this plane and the shuttle ram direction is smallest. Generally, ion spectra peak in the range 19 to 25 eV at the minimum angle between the perpendicular plane and the ram direction. The peak energy decreases smoothly as this angle increases. Weak fluxes are measured above the peak, to energies as high as 150 eV. Within the SPREE energy range, two-dimensional distribution functions of beam arc ions in the perpendicular plane have teardrop shapes, symmetric about the minimum angle to shuttle ram with deep minima in the centers. Variations in the peak energies of differential number fluxes agree with collisionless trajectory analysis, assuming that the ions are H2O+ and allowing for different initial velocities before charge exchange. The lowest densities for beam arc ions occur during periods of purely residual outgassing from the shuttle. Ion densities increase by a factor of 5 during waste water dumps. The highest densities occur during operation of the flash evaporator system when the pickup ion densities in daylight can exceed 105 ions cm-3, about 30% of the estimated ambient plasma density. We also present a nonlinear numerical analysis to study the stability of beam arc generated plasma waves and explain electrostatic spectra measured during previous shuttle flights.¿ 1996 American Geophysical Union