EarthRef.org Reference Database (ERR) -- West & Leeman 1987

Pb and Sr isotopic ratios have been determined for tholeiitic shield-building, alkalic cap, and post-erosional stage lavas from Haleakala Crater. Pb isotopic compositions of the tholeiites overlap those of the alkalic cap lavas, although (super 87) Sr/ (super 86) Sr ratios of these two suites are distinct. Alkalic cap and post-erosional lavas appear to be indistinguishable on the basis of Sr and Pb isotopic composition. Sr and Pb isotopic ratios of Haleakala post-shield-building lavas are positively correlated. Such a trend is previously undocumented for any suite of Hawaiian lavas and contrasts with the general negative correlation observed for data from Hawaiian tholeiites. These relations are consistent with a three-component petrogenetic mixing model. Specifically, it is proposed that magma batches at individual Hawaiian volcanoes formed by: (1) mixing of melts generated from mantle plumes containing two isotopically distinct mantle components (primitive vs. enriched). and (2) subsequent variable degrees Or interaction between these plume melts and a third (MORB signature) mantle reservoir prior to their emplacement in a crustal magma chamber. These observations and inferences provide new constraints on physical models of Hawaiian magmatism. Based on observed temporal isotopic variations of Haleakala lavas, it is suggested that the ratio of enriched: primitive mantle components in the Hawaiian plume source decreases during the waning stages of alkalic volcanism. Over the same time interval, both decreasing melt production and protracted residence of ascending melts within the upper mantle contribute to a systematic increase in the ratio of depleted vs. plume component.

Keywords
alkaline earth metals; East Pacific Ocean Islands; evolution;, geochemistry; Haleakala Crater; Hawaii; isotopes; lava; lead;, Maui; Maui County Hawaii; metals; mixing; Oceania; Pb-206/Pb-204;, Pb-207/Pb-204; Pb-208/Pb-204; Polynesia; radioactive isotopes;, ratios; Sr-87/Sr-86; stable isotopes; strontium; tholeiitic, composition; United States, 02D, Isotope geochemistry