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Newton et al. 1977
Newton, G.P., Newton, G.P., Walker, J.C.G. and Mantas, G.P. (1977). Effects of soft electron precipitation on the distribution of vibrational energy of N2. Journal of Geophysical Research 82: doi: 10.1029/JA082i001p00187. issn: 0148-0227.

We have investigated the direct effect of soft electron precipitation on the nitrogen vibrational distribution and on the rate coefficient for the ion-atom interchange reaction between O+ and N2 using a spectrum of the precipitating electrons characteristic of the dayside cusp region. Substantial increases in the nitrogen vibrational temperature and in the rate of the O+ destruction reaction do not occur unless the flux of incident electrons is as large as 1012 cm-2 s-1. For such large fluxes, departures of the vibrational distribution from a Boltzmann distribution have a significant effect on the rate coefficient. Incidentfluxes less than 1011 cm-2 s-1, such as are usually observed, have little direct effect on nitrogen vibration, although the indirect effect resulting from enhanced electron tmeperatures might be important.

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Journal of Geophysical Research
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