A new inversion method for remote sounding of planetary atmospheres is presented which appears to have several significant advantages over the conventional methods. This method is applicable to high-resolution observations where the spectral lines are fully resolved and is based on matching the calculated slopes of the spectral line profiles with slopes of the observed lines shapes. The method is applied to inversion of ozone absorption lines in the earth's atmosphere, and the results are compared with those obtained by a conventional method. The proposed method is seen to provide a significant improvement in the overall accuracy of the retrieved profiles, with higher vertical resolution and higher levels which may be probed.