The Pioneer Venus probes approached Venus with high relative velocity. As they entered the atmosphere, they were rapidly decelerated by aerodynamic drag, and a great deal of heat was generated. To protect the probe structure and the scientific instruments, a carbon phenolic heat shield was placed on the front of the probes. Because the design of heat shields for planetary entry is a developing technology, thermocouples were placed in the heat shields so that actual and predicted heat shield performance could be compared. The function of the heat shield is discussed, the probe environments during entry into the Venusian atmosphere are described, and some results from the heat shield experiment are presented. It was found that for the most part, the heat shields performed better than expected.