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Fujimaki & Aoki 1984
Fujimaki, H. and Aoki, K. (1984). Partition coefficients of Hf, Zr, and REE between phenocrysts and groundmasses. Journal of Geophysical Research 89: doi: 10.1029/JS089iS01p0B662. issn: 0148-0227.

Partition coefficients of Hf, Zr, and REE between olivine, orthopyroxene, clinopyroxene, plagioclase, garnet, amphibole, ilmenite, phlogopite, and liquid are presented. Samples consist of megacrysts in kimberlite, phenocrysts in alkaline basalts, tholeitic basalts and andesitic to dacitic rocks, and synthetic garnet and clinopyroxene in Hawaiian tholeiites. The Hf-Lu and Zr-Lu elemental fractionations are as large as the Lu-Sm or Lu-Nd fractionation. The Hf and Zr partition coefficients between mafic phenocrysts and liquids are smaller than the Lu partition coefficients, but are similar to the Nd or Sm partition coefficients. The Hf and Zr partition coefficients between ilmenite, phlogopite, and liquid are larger than the Lu partition coefficients for these minerals and their corresponding liquids. The Hf-Zr elemental fractionation does not occur except for extreme fractionation involving Zr-minerals and extremely low fo2. These data have an importment bearing on chronological and petrogenetic tracer studies involving the Lu-Hf isotopic system.

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Abstract

Journal
Journal of Geophysical Research
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American Geophysical Union
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