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Cutter & Cutter 1995
Cutter, G.A. and Cutter, L.S. (1995). Behavior of Dissolved Antimony, Arsenic, and Selenium in the Atlantic-Ocean. Marine Chemistry 49(4): 295-306. doi: 10.1016/0304-4203(95)00019-N.
Vertical profiles for dissolved antimony, arsenic, and selenium were obtained at four stations in the eastern basins of the North and South Atlantic Ocean, and on a surface-water transect from 24 degrees S to 31 degrees N. Total dissolved selenium displays surface-water depletion and deep-water enrichment, with organic selenide (selenium in soluble peptides) being the predominant species in surface waters and selenate predominating in deep waters. Although the concentrations of total selenium in surface waters of the Northern and Southern Hemispheres are similar, the ratio of inorganic to organic selenium is strongly influenced by the intensity of upwelling. Total inorganic arsenic is depleted in the surface waters of all stations, and increases to relatively constant deep-water concentrations (c. 20 nmol/l). In contrast, total inorganic antimony shows surface-water maxima at two stations. Although the average surface-water arsenic and antimony concentrations in the Northern and Southern Hemispheres are identical, there is some evidence for the atmospheric deposition of antimony. Overall, the cycling of the metalloids in the Atlantic is dominated by in situ biotic reactions, and modified by inputs from upwelling and atmospheric deposition.
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Keywords
hydride generation, natural-waters, north-atlantic, estuarine, biogeochemistry, speciation, deposition, chemistry
Journal
Marine Chemistry
http://www.elsevier.com/wps/product/cws_home/503349
Publisher
Elsevier Science
P.O. Box 211
1000 AE Amsterdam
The Netherlands
(+31) 20 485 3757
(+31) 20 485 3432
nlinfo-f@elsevier.com
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