Migration of orogenic or basinal fluids is a recently invoked mechanism to explain the widespread presence of late Paleozoic secondary magnetization in the rocks of North America. Paleomagnetic and geochemical results from the Ordovician Viola Limestone in southern Oklahoma are evaluated to assess the role of basinal fluids in leading to secondary magnetizations in the unit. The Viola Limestone contains what we interpret to be a pervasive Pennsylvanian synfolding magnetization residing in magnetite and a localized Permian magnetization which resides in hematite and occurs in alteration zone around mineralized veins. Both secondary magnetizations are interpreted as chemical remanent magnetizations (CRM) based on low burial temperatures and the presence of authigenic magnetic phases. The relative proportion of the Permian CRM in hematite gradually decreases whereas the magnetite CRM increases with distance from the veins. Fluid inclusion and Sr isotope studies indicate that the vein mineralization (calcite with Mississippi-Valley-type oxides and sulfides) precipitated from basinal fluids which were warm, saline, and radiogenic.

The radiogenic 87Sr/86Sr values of the limestones in the alteration zones, and the fact that there is more significant alteration closer to the veins suggests that the basinal fluids were also responsible for alteration in the limestones. The coincidence of the geochemical and remagnetization trends suggests that the Permian CRM dates the migration of basinal fluids through the veins. Geochemical results from the Viola Limestone containing the pervasive CRM indicate that it is relatively unaltered with no evidence for basinal fluids. The lack of evidence for basinal fluids suggests that other mechanisms for the origin of the pervasive CRM need to be tested. The results of this study indicate that flow of basinal fluids was focused in veins and only locally altered the host limestone. ¿ American Geophysical Union 1993