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Williams et al. 1993
Williams, Q., Hemley, R.J., Kruger, M.B. and Jeanloz, R. (1993). High-pressure infrared spectra of a-quartz, coesite, stishovite, and silica glass. Journal of Geophysical Research 98: doi: 10.1029/93JA02171. issn: 0148-0227.

High-pressure infrared absorption spectra of α-quartz, coesite, stishovite, and SiO2 glass are consistent with the primary compression mechanism of the initially tetrahedrally bonded phases being the bending of the Si-O-Si angle at pressures less than 10--20 GPa. At higher pressures, up to 40 GPa, we observe a decline in the intensity of the infrared SiO4 asymmetric-stretching vibrations (zero pressure frequencies between 1040 and 1220 cm-1) of all three phases, with an increase in the relative amplitude between 700 and 900 cm-1. This change in intensities is attributed to an increase in the average coordination number of silicon through extreme distortion of tetrahedra. At pressures above ~20 GPa, the low-pressure crystalline polymorphs gradually become amorphous, and the infrared spectra provide evidence for an increase in silicon coordination in these high-density amorphous phases. The pressure-amorphized samples prepared from quartz and coesite differ structurally both from each other and from silica glass that has been compressed, and the high pressure spectra indicate that these materials are considerably more disordered than stishovite under comparable pressure conditions. Average mode Gr¿neisen parameters calculated for quartz, stishovite, and fused silica from both infrared and Raman spectra are compatible with the corresponding thermodynamic value of the Gr¿neisen parameter; however, that of coesite is significantly discrepant. ¿ American Geophysical Union 1993

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Abstract

Keywords
Mineral Physics, High-pressure behavior, Mineral Physics, Optical, infrared, and Raman spectroscopy
Journal
Journal of Geophysical Research
http://www.agu.org/journals/jb/
Publisher
American Geophysical Union
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