Liquid explosions, generated by rapid degassing of strongly supersaturated liquids, have been investigated in the laboratory with a view to understanding the basic physical processes operating during bubble nucleation and growth and the subsequent behavior of the expanding two-phase flow. Experiments are carried out in a shock tube and are monitored by high-speed photography and pressure transducers. Theoretical CO2 supersaturations up to 455 times the ambient saturation concentration are generated by a chemical reaction; K2CO3 solution is suddenly injected into an excess of HCl solution in such a way as to mix the two solutions rapidly. Immediately after the injection event, a bubble nucleation delay of a few milliseconds is followed by rapid nucleation and explosive expansion of CO2 bubbles forming a highly heterogeneous foam. Enhanced diffusion due to advection in the flow coupled with continuous mixing of the reactants, and hence on-going bubble nucleation after injection, generates an increasingly accelerating flow until the reactants become depleted at peak accelerations of around 150 g and velocities of about 15 m s-1. Stretching of the accelerating two-phase mixture enhances the mixing. Liberation of CO2 vapor is spatially inhomogeneous leading to ductile fragmentation occurring throughout the flow in regions of greatest gas release as the consequence of the collision and stretching of fluid streams. The violence of the eruptions is controlled by using different concentrations of the HCl and K2CO3 solutions, which alters the CO2 supersaturation and yield and also the efficiency of the mixing process. Peak acceleration is proportional to theoretical supersaturation. Pressure measurements at the base of the shock tube show an initial nucleation delay and a pressure pulse related to the onset of explosive bubble formation. These chemically induced explosions differ from liquid explosions created in other experiments. In explosions caused by sudden depressurization of CO2-saturated water, the bubbles nucleate uniformly throughout the liquid in a single nucleation event. Subsequent bubble growth causes the two-phase mixture to be accelerated upward at nearly constant accelerations. Explosively boiling liquids, in which heterogeneous nucleation is suppressed, experience an evaporation wave which propagates down into the liquid column at constant average velocity. Fragmentation occurs at the sharply defined leading edge of the wavefront. The chemical flows effectively simulate highly explosive volcanic eruptions as they are comparable in terms of flow densities, velocities, accelerations, and in the large range of scales present. The large accelerations cause strong extensional strain and longitudinal deformation. Comparable deformation rates in volcanic systems could be sufficient to approach conditions for brittle fragmentation. Tube pumice is a major component of plinian deposits and ignimbrites and preserves evidence of accelerating flow conditions. ¿ American Geophysical Union 1996