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Horowitz et al. 1977
Horowitz, N.H., Hobby, G.L. and Hubbard, J.S. (1977). Viking on Mars: The carbon assimilation experiments. Journal of Geophysical Research 82: doi: 10.1029/JB082i028p04659. issn: 0148-0227.

A fixation of atmospheric carbon, presumably into organic form, occurs in Martian surface material under conditions approximating the actual Martian ones. The reaction showed the following characteristics: The amount of carbon fixed is small by terrestrial standards; highest yields were observed in the light, but some dark activity was also detected; and heating the surface material to 90¿C for nearly 2 hours had no effect on the reaction, but heating to 175¿C for 3 hours reduced it by nearly 90%. New data from Mars do not support an earlier suggestion that the reaction is inhibited by traces of water. There is evidence of considerable heterogeneity among different samples, but different aliquots from the same sample are remarkably uniform in their carbon-fixing capacity. In view of its thermostability it is unlikely that the reaction is biological.

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Journal of Geophysical Research
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