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Harker 1975
Harker, A.B. (1975). The formation of sulfate in the stratosphere through the gas phase oxidation of sulfur dioxide. Journal of Geophysical Research 80: doi: 10.1029/JC080i024p03399. issn: 0148-0227.

A one-dimensional diffusion model was combined with literature values for the rates of gas phase SO2 oxidation reactions to calculate the stratospheric SO4-- profile. The results showed that the reactions of such trace species as OH and HOO with SO2 are sufficiently fast to produce a sulfate layer above the tropopause similar to the observed Junge layer; the sensitivity of the model to the selection of boundary conditions and eddy diffusion profiles was also investigated.

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Journal
Journal of Geophysical Research
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American Geophysical Union
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