The 22.2- and 31.4-GHz channels of the microwave spectrometer on board the Nibmus 5 earth observatory satellite provide information about the global distribution and character of various types of snow and ice. Observations for the winter and summer of 1973 are presented for both polar regions. Well-defined spectral signatures are found for snow, sea ice, and land ice in Greenland and Antarctica. A simple model with subsurface temperature gradients in a lossy homogeneous dielectric does not account for the observations; internal scattering effects appear to play a dominant role.