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Liu et al. 1983
Liu, S.C., McFarland, M., Kley, D., Zafiriou, O. and Huebert, B. (1983). Tropospheric NOx and O3 budgets in the equatorial Pacific. Journal of Geophysical Research 88. doi: 10.1029/JC088iC02p01360. issn: 0148-0227.

By combining the results of model calculations and simultaneous measurements of O3, NO, HNO3, particulate NO3-, and meteorological parameters in the mid-Pacific, we have investigated the budget and photochemistry of near surface atmospheric ozone and odd nitrogen. The observed decrease of O3 toward the Intertropical Convergence Zone is consistent with the transport of O3 from higher latitude and a photochemical sink for O3 by the reaction between H2O and O(1D). The total deposition flux of odd nitrogen deduced from the data is about 1.3¿109 cm-2 s-1, or 5 MT(N)/yr averaged globally. Most of the deposition flux is due to HNO3 and particulate NO3-. This deposition flux is probably representative of values over most of the Pacific because the HNO3 and particulate NO3- densities measured over the Pacific during the GAMETAG experiments are consistent with our values. Since the residence time of odd nitrogen in the lower troposphere is short, a widely distributed, diffuse source of odd nitrogen is required to balance the deposition flux. It seems that the NO formed by cloud to cloud lightning in the tropical upper troposphere is the most likely source.

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Journal of Geophysical Research
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