An automated gas chromatographic technique to measure the concentrations of chlorofluorocarbon 113 (CFC-113:CCl2FCClF2) dissolved in seawater has been developed. The method also quantifies chlorofluorocarbons 11 and 12 (CFC-11:CCl3F and CFC-12:CCl2F2). Seawater collected from Niskin bottles in ground-glass syringes is stripped by a gas stream and concentrated on a cryogenic trap in the manner of Bullister and Weiss (1988) and Gammon et al. (1982). By isolating and heating the trap, the chlorofluorocarbon compounds are reliberated and injected onto a high-resolution capillary gas chromatographic column, followed by electron-capture detection. The analysis time for each sample is less than 15 min. Surface seawater precisions are 2.9%, 2.4%, and 1.2% for CFC-113, CFC-11, and CFC-12, with detection limits of 0.003--0.004, 0.02, and 0.03--0.05 pmol L-1, respectively. Although these statistics do not compare favorably with other CFC-11 and CFC-12 techniques -1 (Bullister and Weiss, 1988)>, the dynamic ranges of the CFC-113:CFC-11 and CFC-113:CFC-12 ''ventilation ages'' are 20:1, better than that of the best CFC-11:CFC-12 age, albeit with inferior precisions. Estimates of the solubility ratios of CFC-113:CFC-11 and CFC-113:CFC-12 are 0.303 and 1.22, disagreeing with the work of Wisegarver and Gammon (1988), whose CFC-113 results are believed to be boosted by coelution with methyl bromide. The optimum tracer ventilation age resolution is ¿0.9 years for both CFC-113:CFC-11 and CFC-113:CFC-12 from a cast considered in the northeastern Atlantic. A plot of CFC-113:CFC-12 ventilation age is presented on an outcropping isopycnal. A strong correlation with pressure and dissolved oxygen concentration is noted and an oxygen utilization rate between 4.2 and 5.5¿0.4 μmol L-1 yr-1 is implied, depending on the choice of CFC-113 atmospheric history. ¿ American Geophysical Union 1995 |