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Asher & Wanninkhof 1998
Asher, W.E. and Wanninkhof, R. (1998). The effect of bubble-mediated gas transfer on purposeful dual-gaseous tracer experiments. Journal of Geophysical Research 103: doi: 10.1029/98JC00245. issn: 0148-0227.

For air-water gas exchange across unbroken surfaces, the only gas-dependent parameter affecting the transfer velocity is the molecular diffusivity of the transferring species. In contrast, bubble-mediated transfer processes can cause the transfer velocity to depend on both molecular diffusivity and aqueous-phase solubility. This can complicate the analysis of data from dual-gaseous tracer gas transfer experiments. Bubble effects also complicate the estimation of transfer velocities for other gases from the transfer velocity calculated using the dual-tracer data. Herein a method for incorporating the effects of bubble-mediated gas transfer processes on the transfer velocity is presented. This new procedure is used to analyze the data from two recent dual-tracer gas transfer experiments. Transfer velocities that include the effect of bubbles are calculated using the data from two previous oceanic dual-gaseous tracer experiments. Comparing these transfer velocities with transfer velocities calculated by neglecting the effect of bubbles shows that bubble-mediated transfer increased the transfer velocity of helium 3 by 5% at a wind speed of 10.6 m s-1. However, when using the transfer velocities for helium 3 to calculate transfer velocities for carbon dioxide under the same conditions, including the effect of bubbles decreases the transfer velocity of carbon dioxide by 18%. This shows that bubble-mediated transfer does not have a large effect on the analysis of dual-tracer data, but it is important in relating transfer velocities determined using helium 3 and sulfur hexafluoride to transfer velocities of more soluble gases at wind speeds above 10 m s-1. ¿ 1998 American Geophysical Union

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Abstract

Keywords
Oceanography, Physical, Air/sea interactions, Oceanography, Biological and Chemical, Radioactivity and radioisotopes
Journal
Journal of Geophysical Research
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Publisher
American Geophysical Union
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