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Kumer et al. 1996
Kumer, J.B., Mergenthaler, J.L., Roche, A.E., Nightingale, R.W., Zele, F., Gille, J.C., Massie, S.T., Bailey, P.L., Connell, P.S., Gunson, M.R., Abrams, M.C., Toon, G.C., Sen, B., Blavier, J.-F., Smith, S.E. and Taylor, F.W. (1996). Comparison of CLAES preliminary N2O5 data with correlative data and a model. Journal of Geophysical Research 101: doi: 10.1029/95JD03767. issn: 0148-0227.

The cryogenic limb etalon array spectrometer (CLAES) aboard the Upper Atmosphere Research Satellite (UARS) has made near-global measurements of N2O5. Data for 388 days have been processed to version 7 (V7) for the period from January 9, 1992, to April 25, 1993. Results from UARS instruments, including CLAES and the improved stratospheric and mesospheric sounder (ISAMS) provide the first near-global N2O5 measurements. Retrieval below 3.16 mbar is adversely affected by aerosols and above 1.47 mbar by lack of signal and possible instrument effects, so data usage is recommended for just the three ''UARS pressure surfaces'' 3.16, 2.15, and 1.47 mbar. A comparison of the diurnal data variation with the model suggests there are offsets in the data that are to first order diurnally independent. These offsets are tabulated to facilitate subtraction, which is recommended for most data applications. Candidate mechanisms for the offsets are discussed. Comparisons of CLAES data with the offsets subtracted, with profiles obtained by the shuttle-deployed Atmospheric Trace Molecule Spectroscopy (ATMOS) experiment and concurrent ISAMS profiles, and with a profile obtained by the balloon-borne NASA Jet Propulsion Laboratory (JPL) MARK IV instrument, show poorest agreement in equatorial regions at 3.15 mbar where CLAES values are larger by about 30 to 40%. At higher altitudes and latitudes the comparison improves and tends toward consistency with systematic error estimates that are based on instrument and retrieval process characterization and range from 14% at 3.16 mbar to 21% at 1.47 mbar. A similar estimate of random CLAES error ranges from 7% at 3.16 mbar 26% at 1.47 mbar. By comparison, the average values of the error estimates generated by the production processing algorithm at 3.16 and 1.47 mbar are 8 and 36%, respectively, and the average values derived from the observed data variability are 19 and 24%. Confidence is enhanced by the good global scale agreement and correlation of CLAES and ISAMS during an N2O5 enhancement event in early-mid-January 1992 polar winter, in which values >5.5 parts per billion at 3.16 mbar by volume are observed. A description of artifacts that may occur at 3.16 mbar and much less frequently at 2.15 mbar, during this and other enhancement conditions, and the demonstrated approach to eliminate these in future versions, is given in the text. ¿ American Geophysical Union 1996

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Keywords
Atmospheric Composition and Structure, General or miscellaneous
Journal
Journal of Geophysical Research
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American Geophysical Union
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