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Broecker 1993
Broecker, W.S. (1993). Evaluation of the 13C constraint on the uptake of fossil fuel CO2 by the ocean. Global Biogeochemical Cycles 7: doi: 10.1029/93GB01445. issn: 0886-6236.

The proposal by Quay et al. [1992] that the time histories of 13C in atmospheric CO2 and oceanic &Sgr;CO2 provide a constraint on the magnitude of uptake of fossil fuel CO2 by the ocean is examined. Our analysis suggests that, while the potential is there, the data base is too inacurrate to permit a distinction to be made among the carbon budgets currently on the table. Examples are given to demonstrate that the twenty or so percent uncertainties in the size of the effective exchange reservoir and in the magnitudes of the temporal changes in the 13C/12C ratio in atmospheric CO2 and ocean &Sgr;CO2 are just too large to permit a reliable estimate of oceanic uptake of fossil fuel CO2. We conclude that tracer-verified ocean general circulation models offer much better estimates than that based on the 13C budget. ¿ American Geophysical Union 1993

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Abstract

Keywords
Oceanography, Biological and Chemical, Geochemistry, Oceanography, Biological and Chemical, Inorganic marine chemistry, Oceanography, Biological and Chemical, General or miscellaneous
Journal
Global Biogeochemical Cycles
http://www.agu.org/journals/gb/
Publisher
American Geophysical Union
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