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Hollander et al. 1993
Hollander, D.J., McKenzie, J.A., Hsu, K.J. and Huc, A.Y. (1993). Application of an eutrophic lake model to the origin of ancient organic-carbon-rich sediments. Global Biogeochemical Cycles 7: doi: 10.1029/92GB02831. issn: 0886-6236.

In this paper we approach the problem of the origin of organic-carbon-rich sediments by using an integrated isotopic and organic geochemical study of the annual productivity/eutrophication cycle in the water column of Lake Greifen (Switzerland) and the historical expression of such cycles as found in the sediments. The Lake Greifen water column and sediment studies reveal that &Dgr;&dgr;13C carbonate-organic matter is correlated with the hydrogen indices (HI) of kerogens, explicable in terms of changing productivity and preservation of the organic matter, and the CO2 budget of the water body. The lake model implies that, if high productivity in CO2 limited surface waters (high nutrient/CO2 ratio) was controlling the preservation of organic matter, a correlation between decreasing &Dgr;&dgr;13C carbonate-organic matter and increasing HI values may be observed. In contrast, if low to moderate productivity in CO2 unlimited surface waters (low nutrient/CO2 ratio) where bottom water anoxia promotes the preservation of organic matter, a correlation between increasing &Dgr;&dgr;13C carbonate-organic matter and increasing HI values may be observed. Application of this model to two well known Jurassic sequences, gave a correlation of increasing HI values with decreasing &Dgr;&dgr;13C carbonate-organic matter for the Kimmeridge Clay Formation (United Kingdom), and increasing HI values with increasing &Dgr;&dgr;13C carbonate organic matter for the early Toarcian shales (France). This suggests that the controlling factor of the former deposit was high primary bioproductivity and of the latter deposit anoxic bottom water conditions. ¿ American Geophysical Union 1993

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Abstract

Keywords
Atmospheric Composition and Structure, Geochemical cycles
Journal
Global Biogeochemical Cycles
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American Geophysical Union
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