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Winn et al. 1994
Winn, C.D., Mackenzie, F.T., Carrilo, C.J., Sabine, C.L. and Karl, D.M. (1994). Air-sea carbon dioxide exchange in the North Pacific Subtropical Gyre: Impplications for the global carbon budget. Global Biogeochemical Cycles 8: doi: 10.1029/94GB00387. issn: 0886-6236.

The role of the ocean as a sink for anthropogenic carbon dioxide is a subject of intensive investigation and debate. Interest in this process is driven by the need to predict the rate of future increase of atmospheric carbon dioxide and subsequent global climatic change. Although estimates of the magnitude of the oceanic sink for carbon dioxide appear to be converging on a value of ~2 (Gt) C yr1 for the 1980s, a detailed understanding of the temporal and spatial variability in the rate of exchange of carbon dioxide between the ocean and the atmosphere is not available. For example, recent modeling work and direct measurements of air-sea carbon dioxide flux produce very different estimates of the air-sea flux in the northern hemisphere. As a consequence, it has been suggested that a large unidentified oceanic carbon dioxide sink may exist in the North Pacific. As a part of our time series observations in the North Pacific Subtropical Gyre, we have measured dissolved inorganic carbon and titration alkalinity over a four-year period. These measurements constitute the most extensive set of observations of carbon system parameters in the surface waters of the central Pacific Ocean. Our results show that the ocean in the vicinity of the time series site is a sink for atmospheric carbon dioxide. On the basis of these observations, we present a mechanism by which the North Pacific Subtropical Gyre can be a potential sink for ~0.2 Gt C yr-1 of atmospheric carbon dioxide. Although our observations indicate that the North Pacific Subtropical Gyre is a sink for atmospheric carbon dioxide, the magnitude of this oceanic sink for atmospheric carbon dioxide, the magnitude of this oceanic sink is relatively small. Our data and interpretations are therefore consistent with the argument for a relatively large sink during the 1980s in northern hemisphere terrestrial biomass. Another possibility is that the net release of carbon dioxide to the atmosphere owing to land use activities in tropical regions has been overestimated. ¿ American Geophysical Union 1994

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Abstract

Keywords
Oceanography, Physical, Air/sea interactions, Oceanography, Biological and Chemical, Geochemistry, Atmospheric Composition and Structure, Geochemical cycles, Oceanography, General, Climate and interannual variability
Journal
Global Biogeochemical Cycles
http://www.agu.org/journals/gb/
Publisher
American Geophysical Union
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