EarthRef.org Reference Database (ERR)
Development and Maintenance by the EarthRef.org Database Team

Detailed Reference Information
Snider & Huang 1998
Snider, J.R. and Huang, J. (1998). Factors influencing the retention of hydrogen peroxide and molecular oxygen in rime ice. Journal of Geophysical Research 103: doi: 10.1029/97JD02847. issn: 0148-0227.

Vertical transport of many atmospheric trace gases is modulated by retention in solid (ice phase) precipitation during the impaction and freezing (i.e., riming) of supercooled cloud droplets. Here we report field measurements of the concentrations of both hydrogen peroxide (H2O2) and molecular oxygen (O2) in rime ice. Gas retention efficiencies, defined as the ratio of the observed concentration divided by the equilibrium concentration predicted by Henry's law, are presented. Rime ice collections were conducted in a wind tunnel using 3.2-- and 9.5--mm impaction cylinders. Velocities were varied between 9 and 20 m/s and ice substrate temperatures were colder than -3.5 ¿C. Averaged values of the retention efficiencies for H2O2 and O2 were 0.05 and 0.32, respectively. Also discussed are direct measurements of H2O2 volatilization obtained by monitoring increases in gaseous H2O2 associated with droplet impingement and freezing on an impaction grid placed upstream of a gas sampling inlet. The observed relationships between retention and the time interval between droplet impaction suggest that H2O2 and O2 are volatilized subsequent to droplet freezing and prior to burial by continued riming. A comparison of the timescales that are expected to govern retention indicates that solute diffusivities in the solidified droplets are ~10-12 m2 s-1. ¿ 1998 American Geophysical Union

BACKGROUND DATA FILES

Abstract

Keywords
Atmospheric Composition and Structure, Cloud physics and chemistry, Atmospheric Composition and Structure, Biosphere/atmosphere interactions, Atmospheric Composition and Structure, Instruments and techniques, Atmospheric Composition and Structure, Geochemical cycles
Journal
Journal of Geophysical Research
http://www.agu.org/journals/jb/
Publisher
American Geophysical Union
2000 Florida Avenue N.W.
Washington, D.C. 20009-1277
USA
1-202-462-6900
1-202-328-0566
service@agu.org
Click to clear formClick to return to previous pageClick to submit