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Detailed Reference Information |
Kulmala, M., Laaksonen, A. and Pirjola, L. (1998). Parameterizations for sulfuric acid/water nucleation rates. Journal of Geophysical Research 103: doi: 10.1029/97JD03718. issn: 0148-0227. |
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We present parametrized equations for calculation of sulfuric acid/water critical nucleus compositions and homogeneous nucleation rates. The parameterizations are in agreement with the thermodynamically consistent version of classical binary homogeneous nucleation theory <Wilemski, 1984> incorporating the hydration effect. The new parameterizations produce nucleation rates that differ by several orders of magnitude from the rates predicted by other parameterizations available in the literature. Model simulations of atmospheric aerosol formation show that the use of the new parameterizations may in some cases result in simulated nucleation mode particle number densities that are by a factor of 1000 lower than those obtained using the old parameterizations. ¿ 1998 American Geophysical Union |
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Abstract |
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Keywords
Atmospheric Composition and Structure, Aerosols and particles (0345, 4801), Atmospheric Composition and Structure, Cloud physics and chemistry, Atmospheric Composition and Structure, Constituent sources and sinks, Atmospheric Composition and Structure, Troposphere—composition and chemistry |
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Publisher
American Geophysical Union 2000 Florida Avenue N.W. Washington, D.C. 20009-1277 USA 1-202-462-6900 1-202-328-0566 service@agu.org |
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