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Detailed Reference Information |
Jobson, B.T., Parrish, D.D., Goldan, P., Kuster, W., Fehsenfeld, F.C., Blake, D.R., Blake, N.J. and Niki, H. (1998). Spatial and temporal variability of nonmethane hydrocarbon mixing ratios and their relation to photochemical lifetime. Journal of Geophysical Research 103: doi: 10.1029/97JD01715. issn: 0148-0227. |
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The relationship between temporal and spatial variability of C2-C8 nonmethane hydrocarbon mixing ratios and their HO lifetimes (&tgr;) is presented for samples collected during the 1993 North Atlantic Regional Experiment (NARE) and from other urban and remote sites. The C2-C4 alkanes, acetylene and benzene typically define a trend of the form slnx=A&tgr;-b where slnx is the standard deviation of the ln of the mixing ratio. The relationship extended over a wider range of hydrocarbons in winter. The exponent b ranged in value from 0.28¿0.023 for winter urban data where C2-C8 hydrocarbons defined a strongly correlated trend, to 0.56¿0.15 for C2-C4 hydrocarbons at a coastal site in Nova Scotia during NARE. The trends are significantly different from that given by the Junge relationship . Data from the Azores do not display such a trend and were likely influenced by local emissions. Variance trends are a useful analytical tool for examining the validity of hydrocarbon measurements. ¿ 1998 American Geophysical Union |
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Abstract |
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Keywords
Atmospheric Composition and Structure, Troposphere—constituent transport and chemistry |
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Publisher
American Geophysical Union 2000 Florida Avenue N.W. Washington, D.C. 20009-1277 USA 1-202-462-6900 1-202-328-0566 service@agu.org |
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