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Detailed Reference Information |
Stevens, M.H. and Conway, R.R. (1999). Calculated OH A 2S+-X2¿ (0,0) band rotational emission rate factors for solar resonance fluorescence. Journal of Geophysical Research 104: doi: 10.1029/1998JD100073. issn: 0148-0227. |
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The Middle Atmosphere High-Resolution Spectrograph Investigation (MAHRSI) measured vertical density profiles of hydroxyl (OH) by observing OH A2&Sgr;+-X2&Pgr;(0,0) solar resonance fluorescence in the mesosphere near 309 nm <Conwayet al., this issue>. Interpretation of the MAHRSI results requires calculation of the OH(0,0) rotational emission rate factors (g factors) which describe the molecule's fluorescent scattering efficiency. This calculation relies heavily on a solar irradiance measurement with high enough spectral resolution to identify the amount of excitation for each rotational transition (resolving power>3.1¿105). Recent high-resolution ground-based measurements of the solar irradiance and more accurate absolute solar irradiance observations allow for much more accurate g factors. We find that the relative intensities of calculated OH(0,0) rotational g factors are in excellent agreement with MAHRSI spectra. The calculated OH(0,0) band g factor is found to be 3.51¿10-4 s-1 at 200 K, in good agreement with the most recent work on the subject. ¿ 1999 American Geophysical Union |
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Abstract |
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Keywords
Atmospheric Composition and Structure, Middle atmosphere—composition and chemistry, Atmospheric Composition and Structure, Instruments and techniques, Hydrology, Evapotranspiration, Information Related to Geographic Region, Antarctica |
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Publisher
American Geophysical Union 2000 Florida Avenue N.W. Washington, D.C. 20009-1277 USA 1-202-462-6900 1-202-328-0566 service@agu.org |
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