Although there is concern for future stratospheric ozone depletion, several large urban populations are already being exposed to very high UV levels due to geographical factors. In Mexico City, ultraviolet radiation (UV) plays an important role in the generation of high levels of tropospheric ozone and other photochemical pollutants. The measurement of ultraviolet-B radiation in Mexico began in the spring 1993, as a pilot project for ultraviolet-B (UV-B) monitoring and as support for the first Hispanic public information program on the UV index through the Televisa (Mexican television network, which covers the Spanish speaking world). In 1996, based on our preliminary measurements, the Mexico City government commissioned the authors to design the Valley of Mexico UV-monitoring Network. The design of the network is presented. The preliminary measurements show that biologically active (UV-B) solar radiation can reach levels above 5 minimum erythemal dose (MED/hour) or 12 UV index units during spring and summer months. Annual UV measurements have shown seasonal variations of 40% between winter and summer months. Strong attenuation of UV-B radiation at ground level in the urban troposphere has been detected under polluted conditions. Measurements of the morphology of UV-B radiation have been taken at downtown and suburban monitoring stations, over diurnal, monthly and yearly periods. The network measurements show that the downtown UV-B levels are 20% lower than suburban levels on a seasonal basis, but differences can be greater than 40% on polluted days. The relationship between the Total Ozone Mapping Spectrometer (TOMS) total ozone column and tropospheric ozone concentrations in Mexico City is also discussed. ¿ 2000 American Geophysical Union