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Phadnis & Carmichael 2000
Phadnis, M.J. and Carmichael, G.R. (2000). Transport and distribution of primary and secondary nonmethane volatile organic compounds in east Asia under continental outflow conditions. Journal of Geophysical Research 105: doi: 10.1029/1999JD901098. issn: 0148-0227.

A regional scale three-dimensional atmospheric chemistry model is used to study the transport and chemistry of nonmethane volatile organic compounds (NMVOCs) in east Asia. A springtime episode during the month of May 1987 is investigated. The emission estimates of ethane, propane, and ethene from our calculations in east Asia are ~1.6, ~1.3, and ~5.2 Tg C/yr, respectively. The model calculated hydrocarbon mixing ratios are compared with observations from a network of stations in China and Japan and also with the Pacific Exploratory Mission -West B data. The model predictions generally agree favorably with observations over China and Japan, where hydrocarbon mixing ratios are between 1 and 5 ppb. The long-lived C4 alkanes are better modeled than the highly reactive short-lived C3 alkenes having mixing ratios 80% of the pool of oxygenates. The reverse is true at marine locations, where oxidation products of long-lived alkanes dominate. Sensitivity analysis to increase in the NOx and NMVOC emissions suggest that for the simulation conditions of the model, ozone production over most of east Asia is NOx sensitive. A 20--30% increase in ozone is predicted over China for doubling of NOx emissions. ¿ 2000 American Geophysical Union

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Abstract

Keywords
Atmospheric Composition and Structure, Constituent sources and sinks, Atmospheric Composition and Structure, Troposphere—composition and chemistry, Atmospheric Composition and Structure, Troposphere—constituent transport and chemistry, Mathematical Geophysics, Modeling, Atmospheric Composition and Structure, Cloud physics and chemistry
Journal
Journal of Geophysical Research
http://www.agu.org/journals/jb/
Publisher
American Geophysical Union
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